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2-(2-Bromoethyl)-1,3-dioxolane_Molecular_structure_CAS_18742-02-4)
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2-(2-Bromoethyl)-1,3-dioxolane

Catalog No. 230995 Name Sigma Aldrich
CAS Number 18742-02-4 Website http://www.sigmaaldrich.com
M. F. C5H9BrO2 Telephone 1-800-521-8956
M. W. 181.02776 Fax
Purity 96% Email
Storage Chembase ID: 69721

SYNONYMS

Title
2-(2-溴乙基)-1,3-二氧戊环
IUPAC name
2-(2-bromoethyl)-1,3-dioxolane
IUPAC Traditional name
2-(2-bromoethyl)-1,3-dioxolane
Synonyms
3-Bromopropionaldehyde ethylene acetal
2-(2-溴乙基)-1,3-二噁茂烷

DATABASE IDS

PubChem SID 24853846
Beilstein Number 103516
CAS Number 18742-02-4
MDL Number MFCD00003216
EC Number 242-551-1

PROPERTIES

Contains silver wool as stabilizer
Empirical Formula (Hill Notation) C5H9BrO2
Purity 96%
Boiling Point 68-70 °C/8 mmHg(lit.)
Density 1.542 g/mL at 25 °C(lit.)
Flash Point 65 °C
Flash Point 149 °F
Refractive Index n20/D 1.479(lit.)
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H301-H315-H319-H335
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P301 + P310-P305 + P351 + P338
RID/ADR UN 2810 6.1/PG 3
Risk Statements 22-36/37/38
Safety Statements 26
Storage Temperature 2-8°C
Hazard Class 6.1
UN Number 2810
Packing Group 3
German water hazard class 2

DETAILS

Description (English)
Packaging
10, 50 g in glass bottle
Application
Alkylating agent for amines,1 dithianes,2 and carboximides,3 and via the Grignard reagent, aldehydes.4
Used with eynamides and sodium azide in a "one-pot" synthesis of triazoles.
Description (简体中文)
包装
10, 50 g in glass bottle
Application
与炔酰胺和叠氮化钠共同用于三唑的"一锅法"合成。
胺、1二噻烷、2和羧酰亚胺、3醛(通过格氏试剂)的烷基化试剂。4

REFERENCES