(2S,5S)-(-)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone

• Catalog No.: 663107
• CAS Number: 346440-54-8
• M. F.: C15H22N2O
• M. W.: 246.34798
• Purity: 97%

SYNONYMS

• Title: (2S,5S)-(-)-2-叔丁基-3-甲基-5-苄基-4-咪唑烷酮
• IUPAC name: (2S,5S)-5-benzyl-2-tert-butyl-3-methylimidazolidin-4-one
• IUPAC Traditional name: (2S,5S)-5-benzyl-2-tert-butyl-3-methylimidazolidin-4-one
• Synonyms: (2S,5S)-5-苄基-2-叔丁基-3-甲基-4-咪唑烷酮; (2S,5S)-2-叔丁基-3-甲基-5-苯甲基-4-咪唑烷酮; (2S,5S)-2-tert-Butyl-3-methyl-5-phenylmethyl-4-imidazolidinone; (2S,5S)-5-Benzyl-2-tert-butyl-3-methyl-4-imidazolidinone

DATABASE IDS

• PubChem SID: 24884185
• CAS Number: 346440-54-8
• MDL Number: MFCD03426982

PROPERTIES

• Empirical Formula (Hill Notation): C15H22N2O
• Purity: 97%
• Melting Point: 93-100 °C(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Metal-free OrganoCatalyst™ technology for asymmetric catalysis. Catalyzes asymmetric indole alkylations, Friedel-Crafts alkylations, and a broad range of conjugate addition reactions in high enantiomeric excess.1
Used in the 1,4-addition of electron-rich benzenes to unsaturated aldehydes, asymmetric hydride reduction of α,β-unsaturated aldehydes, and α-functionalization of aldehydes.
Packaging
1 g in glass bottle
500 mg in glass bottle
Legal Information
U.S. Pat. 6,369,243 and related patents apply. For research purposes only.
Organocatalyst is a trademark of Materia, Inc.
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts

Description (简体中文)

Application
用于不对称催化反应的无金属 OrganoCatalyst™ 技术。可催化不对称吲哚烷基化、Friedel-Crafts 烷基化和各种共轭加成反应，反应具有高光学纯度。1
用于富电子苯的 1,4-加成反应生成不饱和醛，α,β-不饱和醛的不对称氢化物还原反应，以及醛的 α-官能化反应。
包装
1 g in glass bottle
500 mg in glass bottle
Legal Information
适用美国专利 6,369,243 和相关专利。仅供研究使用。
法律信息
Organocatalyst is a trademark of Materia, Inc.
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts