(2S,5S)-(-)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone

• Catalog No.: 668540
• CAS Number: 415678-40-9
• M. F.: C16H18N2O2
• M. W.: 270.32632
• Purity: 95%

SYNONYMS

• Title: (2S,5S)-(-)-5-苄基-3-甲基-2-(5-甲基-2-呋喃基)-4-咪唑烷酮
• IUPAC name: (2S,5S)-5-benzyl-3-methyl-2-(5-methylfuran-2-yl)imidazolidin-4-one
• IUPAC Traditional name: (2S,5S)-5-benzyl-3-methyl-2-(5-methylfuran-2-yl)imidazolidin-4-one
• Synonyms: (2S,5S)-3-Methyl-2-(5-methyl-2-furanyl)-5-(phenylmethyl)-4-imidazolidinone; (2S,5S)-3-甲基-2-(5-甲基-2-呋喃基)-5-(苯甲基)-4-咪唑烷酮

DATABASE IDS

• MDL Number: MFCD08457653
• PubChem SID: 24884991
• CAS Number: 415678-40-9

PROPERTIES

• Empirical Formula (Hill Notation): C16H18N2O2
• Purity: 95%
• Flash Point: >110 °C
• Flash Point: >230 °F
• Refractive Index: n20/D 1.5598
• GHS Signal Word: Danger
• GHS Hazard statements: H301-H315-H319-H335
• European Hazard Symbols: Toxic (T)
• Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• GHS Precautionary statements: P261-P301 + P310-P305 + P351 + P338
• RID/ADR: UN 2811 6.1/PG 3
• Risk Statements: 25-36/37/38
• Safety Statements: 26-36-45
• Hazard Class: 6.1
• UN Number: 2811
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Application
Highly selective organocatalyst for the Diels-Alder reaction with simple α,β-unsaturated ketones.4
Catalyst for:
• Enantioselective organocatalytic transfer hydrogenation of cycloalkenones with tert-Bu Hantzsch ester as source of hydrogen1
• Alkylation of indoles with an α,β-disubstituted α,β-unsaturated aldehyde in the enantioselective preparation of a selective serotonin reuptake inhibitor2
• MacMillan reaction3
Packaging
1 g in glass bottle
250 mg in glass bottle
Legal Information
U.S. Pat. 6,369,243 and related patents apply. For research purposes only.
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts

Description (简体中文)

Application
用于和简单 α,β-不饱和酮发生 Diels-Alder 反应的高选择性有机催化剂。4
Catalyst for:
• Enantioselective organocatalytic transfer hydrogenation of cycloalkenones with tert-Bu Hantzsch ester as source of hydrogen1
• Alkylation of indoles with an α,β-disubstituted α,β-unsaturated aldehyde in the enantioselective preparation of a selective serotonin reuptake inhibitor2
• MacMillan reaction3
包装
1 g in glass bottle
250 mg in glass bottle
Legal Information
适用美国专利 6,369,243 和相关专利。仅供研究使用。
Protocols & Applications
Metal-free Asymmetric Catalysis using Macmillan Imidazolidinone Organocatalysts