Vinylboronic acid pinacol ester

• Catalog No.: 633348
• CAS Number: 75927-49-0
• M. F.: C8H15BO2
• M. W.: 154.0145
• Purity: 95%

SYNONYMS

• Title: 乙烯基硼酸频哪醇酯
• IUPAC name: 2-ethenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• IUPAC Traditional name: 2-ethenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
• Synonyms: 2-乙烯基-4,4,5,5-四甲基-1,3,2-二氧杂环戊硼烷; 2-Ethenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; 2-Vinyl-4,4,5,5-tetramethyl-1,3,2-dioxaoborolane; 4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane

DATABASE IDS

• MDL Number: MFCD00192492
• PubChem SID: 24882546
• CAS Number: 75927-49-0

PROPERTIES

• Contains: phenothiazine as stabilizer
• Empirical Formula (Hill Notation): C8H15BO2
• Purity: 95%
• Density: 0.908 g/mL at 25 °C(lit.)
• Flash Point: 34 °C
• Flash Point: 93.2 °F
• Refractive Index: n20/D 1.4300(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H226-H317
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P280
• RID/ADR: UN 3272 3/PG 3
• Risk Statements: 10-43
• Safety Statements: 36/37
• Storage Temperature: -20°C
• Hazard Class: 3
• UN Number: 3272
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1, 10 g in glass bottle
Application
Reagent used for
• Suzuki-Miyaura coupling reactions1
• Mizoroki-Heck reactions (cascade reaction)1
• Intramolecular Nozaki-Hiyama-Kishi reactions2
• Stereoselective Cu-catalyzed γ-selective and stereospecific coupling3
• Control of stereoselectivity and mechanistic portrait on intramolecular (4+1)-cycloaddition of dialkoxycarbenes4
• Regio- and stereoselective synthesis of trisubstituted alkenes via gold(I)-catalyzed hydrophosphoryloxylation of haloalkynes followed by Pd-catalyzed consecutive cross-coupling reactions5
• Asymmetric Birch reductive alkylation6Reagent used in Preparation of
• Molecular tubes for lipid sensing7
• Enzymatic inhibitors, antibiotics, receptor analogs, and other biologically significant compounds (including total syntheses)8,9,10,2

Description (简体中文)

包装
1, 10 g in glass bottle
Application
Reagent used for
• Suzuki-Miyaura coupling reactions1
• Mizoroki-Heck reactions (cascade reaction)1
• Intramolecular Nozaki-Hiyama-Kishi reactions2
• Stereoselective Cu-catalyzed γ-selective and stereospecific coupling3
• Control of stereoselectivity and mechanistic portrait on intramolecular (4+1)-cycloaddition of dialkoxycarbenes4
• Regio- and stereoselective synthesis of trisubstituted alkenes via gold(I)-catalyzed hydrophosphoryloxylation of haloalkynes followed by Pd-catalyzed consecutive cross-coupling reactions5
• Asymmetric Birch reductive alkylation6Reagent used in Preparation of
• Molecular tubes for lipid sensing7
• Enzymatic inhibitors, antibiotics, receptor analogs, and other biologically significant compounds (including total syntheses)8,9,10,2