Grubbs Catalyst, 1st Generation

• Catalog No.: 579726
• CAS Number: 172222-30-9
• M. F.: C44H74Cl2P2Ru
• M. W.: 836.981882
• Purity: 97%

SYNONYMS

• Title: Grubbs 1 代催化剂
• IUPAC name: dichlororuthenium; ethenylbenzene; bis(tricyclohexylphosphane)
• IUPAC Traditional name: dichlororuthenium; styrene; bis(tricyclohexylphosphine)
• Synonyms: 二(三环己基膦)亚苄基二氯化钌; 苯基亚甲基双(三环己基膦)二氯化钌; Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium; Bis(tricyclohexylphosphine)benzylidine ruthenium(IV) dichloride

DATABASE IDS

• PubChem SID: 24881009
• CAS Number: 172222-30-9
• MDL Number: MFCD01090946

PROPERTIES

• Empirical Formula (Hill Notation): C43H72Cl2P2Ru
• Purity: 97%
• Melting Point: 153 °C (dec.)(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H228-H315-H319-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P210-P261-P305 + P351 + P338
• Risk Statements: 11-36/37/38
• Safety Statements: 26-36
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
NO BULK ORDERS
Packaging
1, 5 g in glass bottle
Legal Information
US Patent No. 6,111,121 and foreign equivalents apply. Sale of this product conveys to the buyer a limited-use research license. For full details of this license please see sigma-aldrich.com/materialicense. For questions, please contact us at aldrich@sial.com or Materia at info@materia-inc.com.
Application
Metathesis: Ruthenium-Based Metathesis CatalystsHydrosilylation Catalysts
Grubbs 1st Generation Catalyst
• First metathesis catalyst to be widely used in organic synthesis.
• Useful in Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, in Olefin cross metathesis (CM) and Ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions, and ethenolysis of internal olefins.

Description (简体中文)

Other Notes
不接受批量订单
包装
1, 5 g in glass bottle
Legal Information
美国专利 6,111,121 以及国外等同专利均适用。销售该产品可向购买者转让限制使用研究许可。有关该许可的完整详细内容，请访问 sigma-aldrich.com/materialicense。如有疑问，请发送邮件至 aldrich@sial.com 与我们联系，或发送至 info@materia-inc.com 联系 Materia。
Application
Metathesis: Ruthenium-Based Metathesis CatalystsHydrosilylation Catalysts
Grubbs 1st Generation Catalyst
• First metathesis catalyst to be widely used in organic synthesis.
• Useful in Ring-Opening Metathesis Polymerization (ROMP) of strained cyclic olefins, in Olefin cross metathesis (CM) and Ring closing metathesis (RCM) of terminal olefins under a variety of reactions conditions, and ethenolysis of internal olefins.