(R)-T-BINAP

• Catalog No.: 693049
• CAS Number: 99646-28-3
• M. F.: C48H40P2
• M. W.: 678.778722

SYNONYMS

• IUPAC name: (1-{2-[bis(4-methylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(4-methylphenyl)phosphane
• IUPAC Traditional name: (1-{2-[bis(4-methylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(4-methylphenyl)phosphane
• Synonyms: (R)-(+)-2,2′-双(二-对甲苯基膦)-1,1′-联萘; (R)-Tol-BINAP; (R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl

DATABASE IDS

• CAS Number: 99646-28-3
• MDL Number: MFCD01311709

PROPERTIES

• Empirical Formula (Hill Notation): C48H40P2
• Melting Point: 250-255 °C
• Melting Point: 254-258 °C
• Optical Rotation: [α]20/D +162°, c = 0.5 in benzene
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Takasago for research purposes only.
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst involved in studies of the role of excess phosphine ligand in enantioselective conjugate addition of ethylmagnesium bromide and α,β-unsaturated esterReactant serving as a precursor for:
• Catalysts used for reductive amination of ketones
• Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives
• Chiral platinum catalysts for asymmetric Baeyer-Villiger oxidation of cyclic ketones
• CuI-Tol-BINAP catalysts for enantioselective Michael reactions of Grignard reagents to unsaturated esters
• BINAP Pt Dications for cation trapping

Description (简体中文)

包装
100, 500 mg in glass bottle
Legal Information
与 Takasago 联合销售，仅供研究使用。
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst involved in studies of the role of excess phosphine ligand in enantioselective conjugate addition of ethylmagnesium bromide and α,β-unsaturated esterReactant serving as a precursor for:
• Catalysts used for reductive amination of ketones
• Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives
• Chiral platinum catalysts for asymmetric Baeyer-Villiger oxidation of cyclic ketones
• CuI-Tol-BINAP catalysts for enantioselective Michael reactions of Grignard reagents to unsaturated esters
• BINAP Pt Dications for cation trapping