(S)-BINAP

• Catalog No.: 693057
• CAS Number: 76189-56-5
• M. F.: C44H32P2
• M. W.: 622.672402

SYNONYMS

• IUPAC name: {1-[2-(diphenylphosphanyl)naphthalen-1-yl]naphthalen-2-yl}diphenylphosphane
• IUPAC Traditional name: binap
• Synonyms: (S)-(-)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene; (S)-(-)-2,2′-双(二苯膦基)-1,1′-联萘; (S)-(-)-(1,1′-Binaphthalene-2,2′-diyl)bis(diphenylphosphine); (S)-(-)-1,1′-联萘-2,2'-双二苯膦; (S)-(-)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl; (S)-(-)-BINAP

DATABASE IDS

• Beilstein Number: 5321443
• MDL Number: MFCD00010805
• CAS Number: 76189-56-5

PROPERTIES

• Linear Formula: [(C6H5)2PC10H6-]2
• Melting Point: 238-240 °C(lit.)
• Optical Rotation: [α]20/D -222, c = 0.5 in benzene
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Takasago for research purposes only.
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation
• Syntehsis of organophophine oxides as anittumor agents
• SN2 halogenation of hydroxy groups
• Synthesis of BINAP complexes
• Studies of conformational flexibility of BINAP chelates

Description (简体中文)

包装
100, 500 mg in glass bottle
Legal Information
与 Takasago 联合销售，仅供研究使用。
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Reactant involved in:
• Enantioselective and diastereoselective unpoled carbonyl allylation
• Syntehsis of organophophine oxides as anittumor agents
• SN2 halogenation of hydroxy groups
• Synthesis of BINAP complexes
• Studies of conformational flexibility of BINAP chelates