4-Methoxycarbonylphenylboronic acid

• Catalog No.: 594539
• CAS Number: 99768-12-4
• M. F.: C8H9BO4
• M. W.: 179.96566

SYNONYMS

• Title: 4-甲氧羰基苯硼酸
• IUPAC name: [4-(methoxycarbonyl)phenyl]boronic acid
• IUPAC Traditional name: 4-(methoxycarbonyl)phenylboronic acid
• Synonyms: (4-Carbomethoxyphenyl)boronic acid; p-(Methoxycarbonyl)boronic acid; 4-甲酸甲酯苯硼酸; Methyl 4-boronobenzoate; 4-Carbomethoxybenzeneboronic acid; 4-Methoxycarbonylbenzeneboronic acid; 4-borono-benzoic acid 1-methyl ester; p-(Methoxycarbonyl)phenylboronic acid; p-borono-benzoic acid methyl ester; Methyl p-boronobenzoate

DATABASE IDS

• MDL Number: MFCD01632203
• PubChem SID: 24881520
• CAS Number: 99768-12-4

PROPERTIES

• Empirical Formula (Hill Notation): C8H9BO4
• Melting Point: 197-200 °C(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Contains varying amount of anhydride
Packaging
1, 5 g in glass bottle
Application
Reagent used for
• Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence1
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides2
• One-pot ipso-nitration of arylboronic acids3
• Copper-catalyzed nitration4
• Cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling5
• Reagent used in Preparation of
• Biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6†
• Chromenones and their bradykinin B1 antagonistic activit7†
• Pt nanoparticles@Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injectio8†
• Salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor9†

Description (简体中文)

Other Notes
含不定量的酸酐
包装
1, 5 g in glass bottle
Application
Reagent used for
• Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence1
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides2
• One-pot ipso-nitration of arylboronic acids3
• Copper-catalyzed nitration4
• Cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling5
• Reagent used in Preparation of
• Biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6†
• Chromenones and their bradykinin B1 antagonistic activit7†
• Pt nanoparticles@Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injectio8†
• Salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor9†