(S)-BINAPINE

• Catalog No.: 650870
• CAS Number: 528854-26-4
• M. F.: C52H48P2
• M. W.: 734.885042

SYNONYMS

• Title: 二叔丁基四氢联二萘磷
• IUPAC name: (14S)-13-tert-butyl-14-[(12S)-13-tert-butyl-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-12-yl]-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(15),2,4,6,8,10,16,18,20,22-decaene
• IUPAC Traditional name: (14S)-13-tert-butyl-14-[(12S)-13-tert-butyl-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(23),2,4,6,8,10,15,17,19,21-decaen-12-yl]-13-phosphapentacyclo[13.8.0.0^2,^1^1.0^3,^8.0^1^8,^2^3]tricosa-1(15),2,4,6,8,10,16,18,20,22-decaene
• Synonyms: (3S,3'S,4S,4'S,11bS,11'bS)-(+)-4,4′-二-叔丁基-4,4′,5,5′-四氢-3,3′-二-3H-二萘并[2,1-c:1′,2′-e]磷杂庚英; (3S,3’S,4S,4’S,11bS,11’bS)-(+)-4,4′-Di-t-butyl-4,4′,5,5′-tetrahydro-3,3′-bi-3H-dinaphtho[2,1-c:1′,2′-e]phosphepin

DATABASE IDS

• MDL Number: MFCD06658119
• CAS Number: 528854-26-4
• PubChem SID: 24883786

PROPERTIES

• Empirical Formula (Hill Notation): C52H48P2
• Melting Point: >300 °C (dec.)(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• Storage Temperature: 2-8°C
• German water hazard class: 3

DETAILS

Description (English)

Application
Demonstates excellent enantioselectivity and reactivity for the asymmetric hydrogenation of Z-β-aryl(β-acylamino)acrylates.1
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Packaging
100, 500 mg in glass bottle

Description (简体中文)

Application
用于 Z-β-芳基(β-酰氨基)丙烯酸酯的不对称氢化反应中具有优异的对映选择性和反应性。1
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
包装
100, 500 mg in glass bottle