(1R,exo,exo)-3-[N-(3,5-Dimethylphenyl)benzenesulfonamido]isoborneol

• Catalog No.: 41390
• CAS Number: 87420-26-6
• M. F.: C24H31NO3S
• M. W.: 413.57284
• Purity: ≥98.5% (sum of enantiomers, HPLC)

SYNONYMS

• Title: (1R,外,外)-3-[N-(3,5-二甲基苯基)苯亚磺酰氨基]异冰片
• IUPAC name: N-(3,5-dimethylphenyl)-N-[(1S,2R,3S,4R)-3-hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]benzenesulfonamide
• IUPAC Traditional name: N-(3,5-dimethylphenyl)-N-[(1S,2R,3S,4R)-3-hydroxy-4,7,7-trimethylbicyclo[2.2.1]heptan-2-yl]benzenesulfonamide
• Synonyms: (1R,2S,3R)-(+)-3-[N-Benzenesulfonyl-N-(3,5-dimethylphenyl)amino]-2-bornanol; (1R,2S,3R)-(+)-3-[N-苯磺酰基-N-(3,5-二甲基苯基)氨基]-2-莰醇

DATABASE IDS

• Beilstein Number: 4715153
• CAS Number: 87420-26-6
• PubChem SID: 24865881
• MDL Number: MFCD00078990

PROPERTIES

• Empirical Formula (Hill Notation): C24H31NO3S
• Purity: ≥98.5% (sum of enantiomers, HPLC)
• Melting Point: 122-125 °C(lit.)
• Melting Point: 122-125 °C
• Optical Rotation: [α]20/D +65±2°, c = 4% in chloroform
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Auxiliary for very efficient asymmetric reactions: asymmetric alkylation of its esters1; asymmetric conjugate addition to its enoates2,3; hydroxylation of its esters4

Description (简体中文)

Other Notes
用于高效不对称反应的助剂：其酯的不对称烷基化反应1；其烯酸酯的不对称共轭加成反应2,3；其酯的羟基化反应4