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(+)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene_Molecular_structure_CAS_136779-28-7)
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(+)-1,2-Bis[(2S,5S)-2,5-diethylphospholano]benzene

Catalog No. 14734 Name Sigma Aldrich
CAS Number 136779-28-7 Website http://www.sigmaaldrich.com
M. F. C22H36P2 Telephone 1-800-521-8956
M. W. 362.468762 Fax
Purity ~90% (GC) Email
Storage Chembase ID: 139191

SYNONYMS

Title
(+)-1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯
IUPAC name
(2S,5S)-1-{2-[(2S,5S)-2,5-diethylphospholan-1-yl]phenyl}-2,5-diethylphospholane
IUPAC Traditional name
(2S,5S)-1-{2-[(2S,5S)-2,5-diethylphospholan-1-yl]phenyl}-2,5-diethylphospholane
Synonyms
(2S,2′S,5S,5′S)-2,2′,5,5′-四乙基-1,1′-(邻亚苯基)二磷烷
(S,S)-Ethyl-DUPHOS
(S,S)-乙基-DUPHOS
(2S,2′S,5S,5′S)-2,2′,5,5′-Tetraethyl-1,1′-(o-phenylene)diphospholane

DATABASE IDS

Beilstein Number 4814174
PubChem SID 24848817
CAS Number 136779-28-7
MDL Number MFCD00142321

PROPERTIES

Empirical Formula (Hill Notation) C22H36P2
Grade technical
Purity ~90% (GC)
Density 1.010 g/mL at 25 °C
Refractive Index n20/D 1.581
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Application
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Description (简体中文)
Application
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

REFERENCES