L-Selectride® solution

• Catalog No.: 257044
• CAS Number: 38721-52-7
• M. F.: C12H27BLi
• M. W.: 189.09478

SYNONYMS

• Title: L-Selectride® 溶液
• IUPAC name: lithium(1+) ion tris(butan-2-yl)boranuide
• IUPAC Traditional name: lithium(1+) ion tris(sec-butyl)boranuide
• Synonyms: 三仲丁基硼氢化锂 溶液; Lithium tri-sec-butylborohydride solution

DATABASE IDS

• PubChem SID: 24855566
• MDL Number: MFCD00011708
• Beilstein Number: 4007327
• CAS Number: 38721-52-7

PROPERTIES

• Concentration: 1.0 M lithium tri-sec-butylborohydride in THF
• Linear Formula: Li[CH(CH3)CH2CH3]3BH
• Density: 0.89 g/mL at 25 °C
• Flash Point: -17 °C
• Flash Point: 1.4 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H250-H260-H314-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P222-P223-P231 + P232-P370 + P378-P422
• RID/ADR: UN 3394 4.2/PG 1
• Risk Statements: 11-14/15-17-19-34-37
• Safety Statements: 16-26-36/37/39-43-45
• Supplemental Hazard Statements: May form explosive peroxides.
• Hazard Class: 4.2
• UN Number: 3394
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1.8 L in Sure-Pac™
200 mL in Sure-Pac™
Application

• Reducing agent1Reagent for:
• Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters2
• Diastereoselective reduction reactions3
• Hydride reduction of the Danishefsky pyranones4
• Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes5
• Synthesis of alkanols by carbonylation reactions6
Recommended products
Angled septum-inlet adapter Z118206 or straight septum-inlet adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter, 13mm I.D. inlet, Z118192 is recommended.
Legal Information
Selectride is a registered trademark of Sigma-Aldrich Co. LLC

Description (简体中文)

包装
1.8 L in Sure-Pac™
200 mL in Sure-Pac™
Application

• Reducing agent1Reagent for:
• Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters2
• Diastereoselective reduction reactions3
• Hydride reduction of the Danishefsky pyranones4
• Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes5
• Synthesis of alkanols by carbonylation reactions6
Recommended products
推荐使用弯通式隔垫入口接头 Z118206 或直通式隔垫入口接头 Z118141（6mm 内径入口）或直通式隔垫入口接头 Z118192（13mm 内径入口）。
法律信息
Selectride 注册商标 Sigma-Aldrich Co. LLC