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Boron tribromide solution_Molecular_structure_CAS_10294-33-4)
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Boron tribromide solution

Catalog No. 211222 Name Sigma Aldrich
CAS Number 10294-33-4 Website http://www.sigmaaldrich.com
M. F. BBr3 Telephone 1-800-521-8956
M. W. 250.523 Fax
Purity Email
Storage Chembase ID: 107043

SYNONYMS

Title
三溴化硼 溶液
IUPAC name
tribromoborane
IUPAC Traditional name
boron tribromide
Synonyms
Tribromoboron

DATABASE IDS

PubChem SID 24852661
CAS Number 10294-33-4
MDL Number MFCD00011312

PROPERTIES

Concentration 1.0 M in methylene chloride
Empirical Formula (Hill Notation) BBr3
Density 1.467 g/mL at 25 °C
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Pictograms GHS08
GHS Signal Word Danger
GHS Hazard statements H300-H314-H330-H351
European Hazard Symbols Highly toxic Highly toxic (T+)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P260-P264-P280-P284-P301 + P310-P305 + P351 + P338
RID/ADR UN 3390 6.1/PG 1
Risk Statements 14-26/28-35-40
Safety Statements 26-28-36/37/39-45
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 6.1
UN Number 3390
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Application
Used to cleave aryl methyl ethers in a synthesis of a benzopyranobenzopyran from a coumarin scaffold.11
Reactant for preparation of:
• Drug intermediate 6-nitro-L-DOPA1
• Luminescent polystyrene derivatives with sterically protected carbazolylborane moieties2
• High-quality boron-doped graphene via Wurtz-type reductive coupling reaction3
• Mercapto-(+)-methamphetamine haptens for synthesis of (+)-methamphetamine conjugate vaccines with improved epitope densities4
• Micrometer-sized organic molecule-DNA hybrid structures5
• Borane complexes via electrophilic aromatic borylation reactions6
• A 5-HT2C receptor agonist7
• Biphenyl-derivatives possessing tertiary amino groups as β-secretase(BACE1) inhibitors for the treatment of Alzheimer′s disease8
• A highly near-IR region fluorescent p-extended boron aza-dipyrromethene moiety unit9
• Tetrahydroisoquinoline derivatives via intramolecular cyclization of methoxy-substituted N-phenethylimides10
Packaging
10 mL in glass bottle
2 L in Sure/Seal™
2.5 L in glass bottle
4×25, 100, 800 mL in Sure/Seal™
Description (简体中文)
Application
在由香豆素支架合成 benzopyrano benzopyran 类化合物的反应中用于裂解芳基甲基醚。11
Reactant for preparation of:
• Drug intermediate 6-nitro-L-DOPA1
• Luminescent polystyrene derivatives with sterically protected carbazolylborane moieties2
• High-quality boron-doped graphene via Wurtz-type reductive coupling reaction3
• Mercapto-(+)-methamphetamine haptens for synthesis of (+)-methamphetamine conjugate vaccines with improved epitope densities4
• Micrometer-sized organic molecule-DNA hybrid structures5
• Borane complexes via electrophilic aromatic borylation reactions6
• A 5-HT2C receptor agonist7
• Biphenyl-derivatives possessing tertiary amino groups as β-secretase(BACE1) inhibitors for the treatment of Alzheimer′s disease8
• A highly near-IR region fluorescent p-extended boron aza-dipyrromethene moiety unit9
• Tetrahydroisoquinoline derivatives via intramolecular cyclization of methoxy-substituted N-phenethylimides10
包装
10 mL in glass bottle
2 L in Sure/Seal™
2.5 L in glass bottle
4×25, 100, 800 mL in Sure/Seal™

REFERENCES