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(1R)-(+)-Camphorsulfonylimine_Molecular_structure_CAS_107869-45-4)
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(1R)-(+)-Camphorsulfonylimine

Catalog No. 319716 Name Sigma Aldrich
CAS Number 107869-45-4 Website http://www.sigmaaldrich.com
M. F. C10H15NO2S Telephone 1-800-521-8956
M. W. 213.2966 Fax
Purity 99% Email
Storage Chembase ID: 139063

SYNONYMS

Title
(1R)-(+)-樟脑内磺酰亚胺
IUPAC name
(1R)-10,10-dimethyl-3λ6-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene-3,3-dione
IUPAC Traditional name
(1R)-10,10-dimethyl-3λ6-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene-3,3-dione
Synonyms
(7R)-(+)-10,10-二甲基-3-硫杂-4-氮杂三环[5.2.1.01,5]癸-4-烯-3,3-二氧化物
(3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide
(7R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-dioxide
(3aR)-(+)-4,5,6,7-四氢-8,8-二甲基-3H-3a,6-亚甲基-2,1-苯并异噻唑基-2,2-二氧化物

DATABASE IDS

PubChem SID 24859182
Beilstein Number 85297
CAS Number 107869-45-4
MDL Number MFCD00064576

PROPERTIES

Empirical Formula (Hill Notation) C10H15NO2S
Purity 99%
Melting Point 229-230 °C(lit.)
Optical Rotation [α]20/D +34°, c = 1 in chloroform
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Application
(R) and (S) forms are precursors to chiral (camphorsulfonyl)oxaziridines employed in the asymmetric hydroxylation of ester and amide enolates.1
Description (简体中文)
Application
(R) 和 (S) 型是手性(樟脑磺)哑嗪的前体,用于酯和酰胺烯醇化物的不对称羟基化反应。1

REFERENCES