(1R)-(+)-Camphorsulfonylimine

• Catalog No.: 319716
• CAS Number: 107869-45-4
• M. F.: C10H15NO2S
• M. W.: 213.2966
• Purity: 99%

SYNONYMS

• Title: (1R)-(+)-樟脑内磺酰亚胺
• IUPAC name: (1R)-10,10-dimethyl-3λ^6-thia-4-azatricyclo[5.2.1.0^1,^5]dec-4-ene-3,3-dione
• IUPAC Traditional name: (1R)-10,10-dimethyl-3λ^6-thia-4-azatricyclo[5.2.1.0^1,^5]dec-4-ene-3,3-dione
• Synonyms: (7R)-(+)-10,10-二甲基-3-硫杂-4-氮杂三环[5.2.1.01,5]癸-4-烯-3,3-二氧化物; (3aR)-(+)-4,5,6,7-Tetrahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole-2,2-dioxide; (7R)-(+)-10,10-Dimethyl-3-thia-4-azatricyclo[5.2.1.01,5]dec-4-ene 3,3-dioxide; (3aR)-(+)-4,5,6,7-四氢-8,8-二甲基-3H-3a,6-亚甲基-2,1-苯并异噻唑基-2,2-二氧化物

DATABASE IDS

• PubChem SID: 24859182
• Beilstein Number: 85297
• CAS Number: 107869-45-4
• MDL Number: MFCD00064576

PROPERTIES

• Empirical Formula (Hill Notation): C10H15NO2S
• Purity: 99%
• Melting Point: 229-230 °C(lit.)
• Optical Rotation: [α]20/D +34°, c = 1 in chloroform
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Application
(R) and (S) forms are precursors to chiral (camphorsulfonyl)oxaziridines employed in the asymmetric hydroxylation of ester and amide enolates.1

Description (简体中文)

Application
(R) 和 (S) 型是手性(樟脑磺)哑嗪的前体，用于酯和酰胺烯醇化物的不对称羟基化反应。1