(-)-(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyl methyl ether

• Catalog No.: 347019
• CAS Number: 82863-72-7
• M. F.: C25H25FeOP
• M. W.: 428.284161
• Purity: 98%

SYNONYMS

• Title: (-)-(R)-1-[(S)-2-(二苯基膦)二茂铁基]乙基甲基醚
• IUPAC name: λ^2-iron(2+) ion 3-(diphenylphosphanyl)-4-[(1R)-1-methoxyethyl]cyclopenta-2,4-dien-1-ide cyclopenta-2,4-dien-1-ide
• IUPAC Traditional name: λ^2-iron(2+) ion 3-(diphenylphosphanyl)-4-[(1R)-1-methoxyethyl]cyclopenta-2,4-dien-1-ide cyclopentadienide

DATABASE IDS

• MDL Number: MFCD00075375
• CAS Number: 82863-72-7

PROPERTIES

• GHS Signal Word: Warning
• GHS Hazard statements: H302-H312-H332
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P280
• Risk Statements: 20/21/22
• Safety Statements: 36
• German water hazard class: 3
• Empirical Formula (Hill Notation): C25H18FeOP
• Purity: 98%
• Melting Point: 127-128 °C(lit.)
• Optical Rotation: [α]20/D -337°, c = 1 in chloroform

DETAILS

Description (English)

Application
Ligand for the synthesis of optically active binaphthyls,1 and ternaphthalenes2 via asymmetric Grignard cross-coupling.

Description (简体中文)

Application
用于通过不对称格氏交叉偶联反应合成光学活性联萘1和 ternaphthalenes2 的配体。