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Bis[(R)-(-)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]rhodium(I) perchlorate_Molecular_structure_CAS_95156-21-1)
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Bis[(R)-(-)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]rhodium(I) perchlorate

Catalog No. 334928 Name Sigma Aldrich
CAS Number 95156-21-1 Website http://www.sigmaaldrich.com
M. F. C88H64ClO4P4Rh Telephone 1-800-521-8956
M. W. 1447.700904 Fax
Purity 96% Email
Storage Chembase ID: 138839

SYNONYMS

Title
双[(R)-(-)-2,2′-双(二苯基膦基)-1,1′-联萘]高氯酸铑(I)
IUPAC name
λ1-rhodium(1+) ion bis({1-[2-(diphenylphosphanyl)naphthalen-1-yl]naphthalen-2-yl}diphenylphosphane) perchlorate
IUPAC Traditional name
λ1-rhodium(1+) ion bis(binap) perchlorate

DATABASE IDS

CAS Number 95156-21-1

PROPERTIES

Linear Formula [[(C6H5)2PC10H6-]2]2RhClO4
Purity 96%
Melting Point 258-261 °C (dec.)(lit.)
Optical Rotation [α]24/D -109.7°, c = 0.2 in methylene chloride
GHS Pictograms GHS03
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H272-H315-H319-H335
European Hazard Symbols Oxidising Oxidising (O)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P220-P261-P305 + P351 + P338
RID/ADR UN 1479 5.1/PG 2
Risk Statements 8-36/37/38
Safety Statements 17-26-36/37/39
Hazard Class 5.1
UN Number 1479
Packing Group 2
German water hazard class 3

DETAILS

REFERENCES