(-)-Sparteine

• Catalog No.: 415316
• CAS Number: 90-39-1
• M. F.: C15H26N2
• M. W.: 234.38034
• Purity: 99%

SYNONYMS

• Title: (-)-鹰爪豆碱
• IUPAC name: (1S,2R,9S,10S)-7,15-diazatetracyclo[7.7.1.0^2,^7.0^1^0,^1^5]heptadecane
• IUPAC Traditional name: sparteine
• Synonyms: (-)-Lupinidine; (-)-司巴丁

DATABASE IDS

• EC Number: 201-988-8
• MDL Number: MFCD00069653
• CAS Number: 90-39-1
• PubChem SID: 24865990

PROPERTIES

• Empirical Formula (Hill Notation): C15H26N2
• Purity: 99%
• Boiling Point: 137-138 °C/1 mmHg(lit.)
• Density: 1.02 g/mL at 25 °C(lit.)
• Flash Point: 113 °C
• Flash Point: 235.4 °F
• Optical Rotation: [α]20/D -16.5°, c = 10 in ethanol
• Refractive Index: n20/D 1.528(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H302-H312-H332
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P280
• Risk Statements: 20/21/22
• RTECS: WG5950000
• Safety Statements: 36
• German water hazard class: 3

DETAILS

Description (English)

Application
Controls asymmetric lithiation/alkylation of prochiral diphenylmethanes1 and enantioselective deprotonation in preparation of chiral phosphine ligands.2
Organocatalyst compexed with copper (II) for the enantioselective syntheses of nitro aldols (Henry reaction).

Description (简体中文)

Application
与铜(II)络合的有机催化剂，用于硝基羟醛的对映选择性合成（Henry 反应）。
控制前手性二苯甲烷的不对称锂化/烷化反应1以及手性膦配体制备过程中的对映选择性脱质子化反应。2