Dimethyl trimethylsilylmethylphosphonate

• Catalog No.: 375993
• CAS Number: 13433-42-6
• M. F.: C6H17O3PSi
• M. W.: 196.256641
• Purity: 97%

SYNONYMS

• Title: 三甲硅基甲基膦酸二甲酯
• IUPAC name: dimethyl [(trimethylsilyl)methyl]phosphonate
• IUPAC Traditional name: dimethyl (trimethylsilyl)methylphosphonate
• Synonyms: [(Trimethylsilyl)methyl]-phosphonic acid dimethyl ester

DATABASE IDS

• CAS Number: 13433-42-6
• Beilstein Number: 2412153
• MDL Number: MFCD00042921

PROPERTIES

• Linear Formula: (CH3)3SiCH2P(O)(OCH3)2
• Purity: 97%
• Boiling Point: 111-114 °C/21.5 mmHg(lit.)
• Density: 1.024 g/mL at 25 °C(lit.)
• Flash Point: 71 °C
• Flash Point: 159.8 °F
• Refractive Index: n20/D 1.435(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Application
Reactant for:
• Synthesis of phosphonato-phosphine palladacycles1
• Studying the synthetic applications of phosphoryl-stabilized anions2
• Peterson olefination reactions3
• Dilithiation4,5 and transmetalation4

Description (简体中文)

Application
Reactant for:
• Synthesis of phosphonato-phosphine palladacycles1
• Studying the synthetic applications of phosphoryl-stabilized anions2
• Peterson olefination reactions3
• Dilithiation4,5 and transmetalation4