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(3aS,7R,7aS)-7,7a-Dihydro-7-hydroxy-2,2-dimethyl-1,3-benzodioxol-4(3aH)-one_Molecular_structure_CAS_139013-57-3)
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(3aS,7R,7aS)-7,7a-Dihydro-7-hydroxy-2,2-dimethyl-1,3-benzodioxol-4(3aH)-one

Catalog No. 493880 Name Sigma Aldrich
CAS Number 139013-57-3 Website http://www.sigmaaldrich.com
M. F. C9H12O4 Telephone 1-800-521-8956
M. W. 184.18918 Fax
Purity 98% Email
Storage Chembase ID: 138013

SYNONYMS

Title
(3aS,7R,7aS)-7,7a-二氢-7-羟基-2,2-二甲基-1,3-苯并二氧戊环-4(3aH)-酮
IUPAC name
(3aS,7R,7aS)-7-hydroxy-2,2-dimethyl-3a,4,7,7a-tetrahydro-2H-1,3-benzodioxol-4-one
IUPAC Traditional name
(3aS,7R,7aS)-7-hydroxy-2,2-dimethyl-7,7a-dihydro-3aH-1,3-benzodioxol-4-one

DATABASE IDS

CAS Number 139013-57-3
MDL Number MFCD01863551

PROPERTIES

Concentration 0.2 g/mL in 0.1 M phosphate buffer
Empirical Formula (Hill Notation) C9H12O4
Purity 98%
pH 8.5(adjusted to)
MSDS Link Download
German water hazard class 3

DETAILS

Description (English)
Reconstitution
To recover the pure product from the suspension:(1)Thaw the frozen suspension and filter the solid. (2) Rinse bottle with a few milliliters of base-washed (aqueous Na2CO3) ethyl acetate. (3) Use the rinsing to wash the solid. (4) Collect solid. (5) To further collect more product from the filtrate: extract filtratewith equal volumes of base-washed (aqueous Na2CO3) ethyl acetate (repeat three times). (6) Dry the ethyl acetate extract over MgSO4. (7) Evaporate the solvent - DO NOT HEAT! (8) Combine solids collected from the suspension and the filtrate. Pure crystals should be stored at -78° C. A suspension of the product in phosphate buffer is stable at 0° C.
Physical form
A suspension in phosphate buffer.
Description (简体中文)
Reconstitution
要从悬浮液中回收纯产物:(1) 将冰冻悬浮液融化并过滤出固体。(2) 用几毫升碱性(含水 Na2CO3)乙酸乙酯洗液冲洗瓶子。(3) 用清水洗涤固体。(4) 收集固体。(5) 从滤出液中进一步收集更多产物:用等体积碱性(含水 Na2CO3)乙酸乙酯洗液抽提滤出液(重复三次)。(6) 将乙酸乙酯抽提物置于 MgSO4 上干燥。(7) 待溶剂蒸发-不要加热!(8) 合并从悬浮液和滤出液中收集的固体。纯晶体应保存于 -78°C。产物的磷酸盐缓冲液悬浮液在 0°C 时稳定。
Physical form
磷酸盐缓冲悬浮液。

REFERENCES