Doyle dirhodium catalyst, Rh2(5S-MEPY)4

• Catalog No.: 424420
• CAS Number: 132435-65-5
• M. F.: C24H32N4O12Rh2
• M. W.: 774.34148

SYNONYMS

• Title: 二铑催化剂，Rh2(5S-MEPY)4
• IUPAC name: 3,10,16,22-tetramethyl 7λ^3,14λ^3,20λ^3,26λ^3-tetraoxa-2,9,15,21-tetraaza-1,8-dirhodaoctacyclo[6.6.6.6^1,^8.0^1,^8.0^2,^6.0^9,^1^3.0^1^5,^1^9.0^2^1,^2^5]hexacosa-6,13,19,25-tetraene-3,10,16,22-tetracarboxylate
• IUPAC Traditional name: 3,10,16,22-tetramethyl 7λ^3,14λ^3,20λ^3,26λ^3-tetraoxa-2,9,15,21-tetraaza-1,8-dirhodaoctacyclo[6.6.6.6^1,^8.0^1,^8.0^2,^6.0^9,^1^3.0^1^5,^1^9.0^2^1,^2^5]hexacosa-6,13,19,25-tetraene-3,10,16,22-tetracarboxylate
• Synonyms: Dirhodium(II)tetrakis[methyl 2-pyrrolidone-5(S)-carboxylate], acetonitrile/2-propanol complex; 二铑四[2-吡咯烷酮-5(S)-羧酸甲酯]，乙腈/2-丙醇络合物

DATABASE IDS

• CAS Number: 132435-65-5

PROPERTIES

• Empirical Formula (Hill Notation): C24H32N4O12Rh2
• GHS Signal Word: Danger
• GHS Hazard statements: H301-H311-H315-H319-H331-H335
• European Hazard Symbols: Toxic (T)
• Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• GHS Precautionary statements: P261-P280-P301 + P310-P305 + P351 + P338-P311
• Risk Statements: 23/24/25-36/37/38-41
• Safety Statements: 22-26-36/37/39-45
• German water hazard class: 3

DETAILS

Description (English)

Application
Chiral catalyst used for highly enantioselective intramolecular cyclopropanations, intermolecular addition reactions, and intramolecular carbon-hydrogen insertion reactions. Also employed in the synthesis of lactones and lactams in high diastereo-, regio-, and enantioselectivities. For a recent review, see Aldrichimica Acta 1
Other Notes
For research purposes only-Not for Use in Humans or in Human Clinical Trials.Under Special Agreement with Regis Technologies, Inc.
Legal Information
Sold under license from Regis Technologies, Inc.

Description (简体中文)

Application
用于高效对映选择性分子内环丙烷化、分子间加成反应以及分子内碳氢键插入反应的手性催化剂。也用于在高非对映立体选择性、高区域选择性和高对映选择性条件下合成内酯和内酰胺。最新综述请参阅 Aldrichimica Acta1
Other Notes
仅用于研究目的，禁止用于人体和人体临床试验。遵守与 Regis Technologies，Inc. 的特别协议
Legal Information
经 Regis Technologies，Inc. 授权销售