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Ethyl diazoacetate_Molecular_structure_CAS_623-73-4)
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Ethyl diazoacetate

Catalog No. E22201 Name Sigma Aldrich
CAS Number 623-73-4 Website http://www.sigmaaldrich.com
M. F. C4H6N2O2 Telephone 1-800-521-8956
M. W. 114.10264 Fax
Purity Email
Storage Chembase ID: 130276

SYNONYMS

Title
重氮乙酸乙酯
IUPAC name
ethyl 2-diazoacetate
IUPAC Traditional name
ethyl diazoacetate
Synonyms
DAAE

DATABASE IDS

Beilstein Number 107654
MDL Number MFCD00001989
CAS Number 623-73-4
PubChem SID 24894459

PROPERTIES

Contains ≥13 wt. % dichloromethane
Linear Formula N=N=CHCOOC2H5
Boiling Point 140-141 °C/720 mmHg(lit.)
Density 1.085 g/mL at 25 °C(lit.)
Flash Point 47 °C
Flash Point 116.6 °F
Melting Point -22 °C(lit.)
Refractive Index n20/D 1.46(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Signal Word Warning
GHS Hazard statements H226-H242-H302-H351
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
GHS Precautionary statements P281
RID/ADR UN 1993 3/PG 3
Risk Statements 5-10-22-40
Safety Statements 36/37
Storage Temperature 2-8°C
Hazard Class 3
UN Number 1993
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Application
Reagent for ruthenium-catalyzed asymmetric cyclopropanation of alkenes.1
New Diazoacetate Formulations
Packaging
20, 100 g in poly bottle
5 g in glass bottle
Description (简体中文)
Application
用于烯烃的钌催化不对称环丙烷化试剂。1
New Diazoacetate Formulations
包装
20, 100 g in poly bottle
5 g in glass bottle

REFERENCES