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N-Fmoc-L-valinol_Molecular_structure_CAS_160885-98-3)
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N-Fmoc-L-valinol

Catalog No. 445673 Name Sigma Aldrich
CAS Number 160885-98-3 Website http://www.sigmaaldrich.com
M. F. C20H23NO3 Telephone 1-800-521-8956
M. W. 325.40152 Fax
Purity 97% Email
Storage Chembase ID: 137242

SYNONYMS

Title
N-Fmoc-L-缬氨醇
IUPAC name
9H-fluoren-9-ylmethyl N-[(2S)-1-hydroxy-3-methylbutan-2-yl]carbamate
IUPAC Traditional name
9H-fluoren-9-ylmethyl N-[(2S)-1-hydroxy-3-methylbutan-2-yl]carbamate
Synonyms
(S)-2-(Fmoc-amino)-3-methyl-1-butanol
N-(9-Fluorenylmethoxycarbonyl)-L-valinol
(S)-2-(Fmoc-氨基)-3-甲基-1-丁醇
N-(9-芴甲氧羰基)-L-缬氨醇

DATABASE IDS

Beilstein Number 7041232
CAS Number 160885-98-3
MDL Number MFCD00235961

PROPERTIES

Empirical Formula (Hill Notation) C20H23NO3
Purity 97%
Melting Point 129-133 °C(lit.)
Optical Rotation [α]20/D -20°, c = 1 in chloroform
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Application
Starting material for the synthesis of enantiopure homo-β-amino acids.1,2 Used in the efficient synthesis of enantiopure tetrahydroisoquinolines.3 Intermediate in the one-pot conversion of amino acid carbamates to N-derivatized 2-oxazolidinones.4
Description (简体中文)
Application
合成对映纯 β-高氨基酸的原料。1,2用于对映纯四氢异喹啉类化合物的高效合成。3一锅法将氨基酸氨基甲酸酯类化合物转化为 N-衍生 2-噁唑烷酮类化合物的中间体。4

REFERENCES