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Diisobutylaluminum hydride solution_Molecular_structure_CAS_1191-15-7)
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Diisobutylaluminum hydride solution

Catalog No. 256838 Name Sigma Aldrich
CAS Number 1191-15-7 Website http://www.sigmaaldrich.com
M. F. C8H19Al Telephone 1-800-521-8956
M. W. 142.217998 Fax
Purity Email
Storage Chembase ID: 127050

SYNONYMS

Title
二异丁基氢化铝 溶液
IUPAC name
bis(2-methylpropyl)alumane
IUPAC Traditional name
diisobutylaluminium hydride
Synonyms
DIBAL-H
DIBAL

DATABASE IDS

Beilstein Number 4123663
CAS Number 1191-15-7
MDL Number MFCD00008928

PROPERTIES

Concentration 1.0 M in cyclohexane
Linear Formula [(CH3)2CHCH2]2AlH
Density 0.781 g/mL at 25 °C
Flash Point -18 °C
Flash Point -1 °F
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-14/15-34
Safety Statements 16-26-27-36/37/39-45
Hazard Class 4.3
UN Number 3399
Packing Group 1

DETAILS

Description (English)
Application
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides.1 O-Debenzylation and ring opening of perbenzylated furanosides.2 Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.3
Packaging
200 mL in Sure-Pac™
Recommended products
Angled septum-inlet adapter Z118206 or straight septum-inlet adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter, 13mm I.D. inlet, Z118192 is recommended.
Description (简体中文)
Application
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides.1 O-Debenzylation and ring opening of perbenzylated furanosides.2 Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.3
包装
200 mL in Sure-Pac™
Recommended products
建议使用弯通式隔垫入口接头 Z118206 或直通式隔垫入口接头 Z118141(6mm 内径入口)或直通式隔垫入口接头 Z118192(13mm 内径入口)。

REFERENCES