Tetranitromethane

• Catalog No.: T25003
• CAS Number: 509-14-8
• M. F.: CN4O8
• M. W.: 196.0327

SYNONYMS

• Title: 四硝基甲烷
• IUPAC name: tetranitromethane
• IUPAC Traditional name: tetranitromethane
• Synonyms: NSC 16146; TNM

DATABASE IDS

• CAS Number: 509-14-8
• EC Number: 208-094-7
• MDL Number: MFCD00007391
• PubChem SID: 24900040

PROPERTIES

• Linear Formula: C(NO2)4
• Boiling Point: 126 °C(lit.)
• Density: 1.637 g/mL at 25 °C(lit.)
• Flash Point: 113 °C
• Flash Point: 235.4 °F
• Melting Point: 13-14 °C(lit.)
• Refractive Index: n20/D 1.438(lit.)
• Vapor Pressure: 8.4 mmHg ( 20 °C)
• GHS Signal Word: Danger
• GHS Hazard statements: H271-H301-H315-H319-H330-H335-H351
• European Hazard Symbols: Oxidising (O)
• European Hazard Symbols: Highly toxic (T+)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P220-P260-P281-P284-P301 + P310-P305 + P351 + P338
• RID/ADR: UN 1510 5.1/PG 1
• Risk Statements: 8-25-26-36/37/38-40
• RTECS: PB4025000
• Safety Statements: 17-28-36/37-45
• Storage Temperature: 2-8°C
• Hazard Class: 5.1
• UN Number: 1510
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Application
Reagent for nitration of enol silyl ethers7 and aromatic compounds.8 Employed in the photooxidation of sulfides to sulfoxides.9
Reactant involved in:
• Nitration of electrophilic alkenes1
• Reactions with B-alkylcatecholboranes forming oxime ethers2
• Heterocyclization of electrophilic alkenes3
• Ring opening of aziridines4
• Acts as an electron acceptor in the mechanism of aerobic visible light formic acid oxidation5
• Reactions with vinyl ketones6
Packaging
1, 5 g in glass bottle

Description (简体中文)

Application
烯醇硅醚7和芳香族化合物的硝化试剂。8用于硫化物到亚砜的光氧化反应。9
Reactant involved in:
• Nitration of electrophilic alkenes1
• Reactions with B-alkylcatecholboranes forming oxime ethers2
• Heterocyclization of electrophilic alkenes3
• Ring opening of aziridines4
• Acts as an electron acceptor in the mechanism of aerobic visible light formic acid oxidation5
• Reactions with vinyl ketones6
包装
1, 5 g in glass bottle