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Iron(0) pentacarbonyl

Catalog No. 481718 Name Sigma Aldrich
CAS Number 13463-40-6 Website http://www.sigmaaldrich.com
M. F. C5FeO5 Telephone 1-800-521-8956
M. W. 195.8955 Fax
Purity >99.99% trace metals basis Email
Storage Chembase ID: 123422

SYNONYMS

Title
五羰基铁
IUPAC name
pentakis(methanidylidyneoxidanium) iron
IUPAC Traditional name
pentakis(carbon monoxide) iron
Synonyms
Iron(0) carbonyl
羰基铁
Pentacarbonyliron(0)
五羰基铁

DATABASE IDS

EC Number 236-670-8
MDL Number MFCD00011001
CAS Number 13463-40-6
PubChem SID 24871777

PROPERTIES

Linear Formula Fe(CO)5
Purity >99.99% trace metals basis
Auto Ignition Point 122 °F
Boiling Point 103 °C(lit.)
Density 1.49 g/mL at 25 °C(lit.)
Flash Point -15 °C
Flash Point 5 °F
Melting Point -20 °C(lit.)
Refractive Index n20/D 1.5196(lit.)
Vapor Density 6.74 (vs air)
Vapor Pressure 35 mmHg ( 25 °C)
Vapor Pressure 40 mmHg ( 30.3 °C)
GHS Pictograms GHS02
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H225-H300 + H330-H311
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Highly toxic Highly toxic (T+)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P260-P264-P280-P284-P301 + P310
RID/ADR UN 1994 6.1/PG 1
Risk Statements 11-24-26/28
RTECS NO4900000
Safety Statements 16-26-28-36/37/39-45
Storage Temperature 2-8°C
Hazard Class 6.1
UN Number 1994
Packing Group 1
German water hazard class 2

DETAILS

Description (English)
General description
Atomic number of base material: 26 Iron
Packaging
25, 100 mL in Sure/Seal™
Application
Reactant for:
• Addition reactions1
• Decomposition via photolysis2
• Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition3
• Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides4
• Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions5
Protocols & Applications
Chemical Synthesis of Monodisperse Magnetic Nanoparticles
Description (简体中文)
General description
Atomic number of base material: 26 Iron
包装
25, 100 mL in Sure/Seal™
Application
Reactant for:
• Addition reactions1
• Decomposition via photolysis2
• Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition3
• Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides4
• Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions5
Protocols & Applications
Chemical Synthesis of Monodisperse Magnetic Nanoparticles

REFERENCES