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Tris[N,N-bis(trimethylsilyl)amide]cerium(III)_Molecular_structure_CAS_41836-21-9)
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Tris[N,N-bis(trimethylsilyl)amide]cerium(III)

Catalog No. 547786 Name Sigma Aldrich
CAS Number 41836-21-9 Website http://www.sigmaaldrich.com
M. F. C18H54CeN3Si6 Telephone 1-800-521-8956
M. W. 621.27046 Fax
Purity 96% Email
Storage Chembase ID: 136708

SYNONYMS

Title
三[N,N-双(三甲基硅基)酰胺]铈(III)
IUPAC name
2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-ceraheptan-4-amine
IUPAC Traditional name
2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-ceraheptan-4-amine
Synonyms
1,1,1-Trimethyl-N-(trimethylsilyl)silanamine cerium(III) salt

DATABASE IDS

CAS Number 41836-21-9
PubChem SID 24878979
MDL Number MFCD03411241

PROPERTIES

GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H228-H261-H314
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P210-P231 + P232-P280-P305 + P351 + P338-P310-P422
RID/ADR UN 3396 4.3/PG 2
Risk Statements 11-14/15-34
Safety Statements 7/8-16-26-36/37/39-43-45
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 4.3
UN Number 3396
Packing Group 2
German water hazard class 3
Linear Formula Ce(N(Si(CH3)3)2)3
Purity 96%
Apperance solid
Flash Point 2 °C
Flash Point 35.6 °F
Melting Point 132-140 °C(lit.)

DETAILS

Description (English)
Packaging
1 g in glass bottle
Application
Reactant for synthesis of:
• Amidocerium(IV) oxides1
• Sterically encumbered N-heterocyclic carbene ligands2
• Lanthanide imidodiphosphinate complexes with electroluminescent properties3
• Lanthanide complexes of an oxazoline-phenoxide hybrid chelate4Reactant for:
• One-electron oxidation to produce tetravalent cerium compounds5
• Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes6
Description (简体中文)
包装
1 g in glass bottle
Application
Reactant for synthesis of:
• Amidocerium(IV) oxides1
• Sterically encumbered N-heterocyclic carbene ligands2
• Lanthanide imidodiphosphinate complexes with electroluminescent properties3
• Lanthanide complexes of an oxazoline-phenoxide hybrid chelate4Reactant for:
• One-electron oxidation to produce tetravalent cerium compounds5
• Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes6

REFERENCES