Tris[N,N-bis(trimethylsilyl)amide]cerium(III)

• Catalog No.: 547786
• CAS Number: 41836-21-9
• M. F.: C18H54CeN3Si6
• M. W.: 621.27046
• Purity: 96%

SYNONYMS

• Title: 三[N,N-双(三甲基硅基)酰胺]铈(III)
• IUPAC name: 2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-ceraheptan-4-amine
• IUPAC Traditional name: 2,2,6,6-tetramethyl-N,N,3,5-tetrakis(trimethylsilyl)-3,5-diaza-2,6-disila-4-ceraheptan-4-amine
• Synonyms: 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine cerium(III) salt

DATABASE IDS

• CAS Number: 41836-21-9
• PubChem SID: 24878979
• MDL Number: MFCD03411241

PROPERTIES

• GHS Signal Word: Danger
• GHS Hazard statements: H228-H261-H314
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P210-P231 + P232-P280-P305 + P351 + P338-P310-P422
• RID/ADR: UN 3396 4.3/PG 2
• Risk Statements: 11-14/15-34
• Safety Statements: 7/8-16-26-36/37/39-43-45
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3396
• Packing Group: 2
• German water hazard class: 3
• Linear Formula: Ce(N(Si(CH3)3)2)3
• Purity: 96%
• Apperance: solid
• Flash Point: 2 °C
• Flash Point: 35.6 °F
• Melting Point: 132-140 °C(lit.)

DETAILS

Description (English)

Packaging
1 g in glass bottle
Application
Reactant for synthesis of:
• Amidocerium(IV) oxides1
• Sterically encumbered N-heterocyclic carbene ligands2
• Lanthanide imidodiphosphinate complexes with electroluminescent properties3
• Lanthanide complexes of an oxazoline-phenoxide hybrid chelate4Reactant for:
• One-electron oxidation to produce tetravalent cerium compounds5
• Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes6

Description (简体中文)

包装
1 g in glass bottle
Application
Reactant for synthesis of:
• Amidocerium(IV) oxides1
• Sterically encumbered N-heterocyclic carbene ligands2
• Lanthanide imidodiphosphinate complexes with electroluminescent properties3
• Lanthanide complexes of an oxazoline-phenoxide hybrid chelate4Reactant for:
• One-electron oxidation to produce tetravalent cerium compounds5
• Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes6