Methoxy(cyclooctadiene)rhodium(I) dimer

• Catalog No.: 661058
• CAS Number: 12148-72-0
• M. F.: C18H30O2Rh2
• M. W.: 484.2406

SYNONYMS

• Title: 甲氧基(环辛二烯)铑(I)二聚体
• IUPAC name: bis(cycloocta-1,5-diene); bis(methoxyrhodium)
• IUPAC Traditional name: bis(1,5-cyclooctadiene); bis(methoxyrhodium)
• Synonyms: [Rh(OMe)(1,5-cod)]2

DATABASE IDS

• MDL Number: MFCD08457639
• PubChem SID: 24884497
• CAS Number: 12148-72-0

PROPERTIES

• Empirical Formula (Hill Notation): C18H30O2Rh2
• Melting Point: 192-225 °C
• German water hazard class: 3

DETAILS

Description (English)

Application
Precursor for organorhodium(I) species, catalyst for cascade1,4-addition-aldol reaction, 1,4-addition of alcohols, and hydroformylation
Rhodium catalyst employed in the cyclization of cyano-substituted unsaturated esters in the presence of aryl 9-BBN leading to 5- and 6-membered β-enamino esters.
Efficient and Selective Catalysts for Asymmetric Synthesis
Packaging
1 g in glass bottle
250 mg in glass bottle

Description (简体中文)

Application
Precursor for organorhodium(I) species, catalyst for cascade1,4-addition-aldol reaction, 1,4-addition of alcohols, and hydroformylation
铑催化剂，用于在芳基 9-BBN 存在的情况下进行腈取代不饱和酯的环化反应，生成 5 元和 6 元 β-烯胺酯。
Efficient and Selective Catalysts for Asymmetric Synthesis
包装
1 g in glass bottle
250 mg in glass bottle