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2,3-Bis[(2R,5R)-2,5-dimethylphospholano]-N-benzylmaleimide(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate_Molecular_structure_CAS_1111760-66-7)
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2,3-Bis[(2R,5R)-2,5-dimethylphospholano]-N-benzylmaleimide(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Catalog No. 669709 Name Sigma Aldrich
CAS Number 1111760-66-7 Website http://www.sigmaaldrich.com
M. F. C31H43BF4NO2P2Rh Telephone 1-800-521-8956
M. W. 713.3362548 Fax
Purity ≥95% (31P-NMR) Email
Storage Chembase ID: 135698

SYNONYMS

Title
2,3-双[(2R,5R)-2,5-二甲基磷]-N-苯甲基马来酰亚胺(1,5-环辛二烯)四氟硼酸铑(I)
IUPAC name
λ1-rhodium(1+) ion 1-benzyl-3,4-bis[(2R,5R)-2,5-dimethylphospholan-1-yl]-2,5-dihydro-1H-pyrrole-2,5-dione cycloocta-1,5-diene tetrafluoroboranuide
IUPAC Traditional name
λ1-rhodium(1+) ion 1,5-cyclooctadiene 1-benzyl-3,4-bis[(2R,5R)-2,5-dimethylphospholan-1-yl]pyrrole-2,5-dione tetrafluoroborate
Synonyms
3,4-Bis[(2R,5R)-2,5-dimethylphospholanyl]-1-benzyl-1H-pyrrol-2,5-dion(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
catASium® MNBn(R)Rh
3,4-双[(2R,5R)-2,5-二甲基磷烷基]-1-苄基-1H-吡咯-2,5-二酮(1,5-环辛二烯)四氟硼酸铑(I)

DATABASE IDS

MDL Number MFCD10567386
CAS Number 1111760-66-7

PROPERTIES

Empirical Formula (Hill Notation) C31H43BF4NO2P2Rh
Purity ≥95% (31P-NMR)
Purity 95%
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26
German water hazard class 3

DETAILS

Description (English)
General description
sold in collaboration with Solvias AG
Application
Essential Elements for Asymmetric Hydrogenations
Legal Information
catASium is a registered trademark of Evonik Degussa GmbH
Description (简体中文)
General description
与 Sovias AG 联合销售
Application
Essential Elements for Asymmetric Hydrogenations
法律信息
catASium 注册商标 Evonik Degussa GmbH

REFERENCES