(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene

• Catalog No.: 672254
• CAS Number: 862499-50-1
• M. F.: C22H30O
• M. W.: 310.473
• Purity: ≥98%

SYNONYMS

• Title: (1S,4S,8S)-5-苄基-8-甲氧基-1,8-二甲基-2-(2′-甲基丙基)-双环[2.2.2]辛-2,5-二烯
• IUPAC name: (1S,4S,8S)-5-benzyl-8-methoxy-1,8-dimethyl-2-(2-methylpropyl)bicyclo[2.2.2]octa-2,5-diene
• IUPAC Traditional name: (1S,4S,8S)-5-benzyl-8-methoxy-1,8-dimethyl-2-(2-methylpropyl)bicyclo[2.2.2]octa-2,5-diene
• Synonyms: (1S,4S,8S) Carreira DOLEFIN 配体; (1S,4S,8S)-5-苄基-2-异丁基-8-甲氧基-1,8-二甲基-2-双环[2.2.2]辛-2,5-二烯; (1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethyl-2-bicyclo[2.2.2]octa-2,5-diene; (1S,4S,8S) Carreira DOLEFIN Ligand; (1S,4S,8S)--5-Benzyl-8-methoxy-1,8-dimethyl-2-(2′-methylpropyl)-bicyclo[2.2.2]octa-2,5-diene

DATABASE IDS

• CAS Number: 862499-50-1
• MDL Number: MFCD09265063
• PubChem SID: 24885112

PROPERTIES

• Empirical Formula (Hill Notation): C22H30O
• Optical Purity: enantiomeric ratio: >99:1
• Purity: ≥98%
• Optical Rotation: [α]20/D -98±5°, c = 0.7 in chloroform
• Personal Protective Equipment: Eyeshields, Gloves
• German water hazard class: 3

DETAILS

Description (English)

Application
When used in conjunction with Rh precatalysts, selectively perform asymmetric conjugate addition to unsaturated esters and aldehydes.1,2
Carreira DOLEFIN Ligands

Description (简体中文)

Application
与铑预催化剂配合使用，选择性地进行不对称共轭加成，生成不饱和酯和醛。1,2
Carreira DOLEFIN Ligands