Bromo(tri-tert-butylphosphine)palladium(I) dimer

• Catalog No.: 677728
• CAS Number: 185812-86-6
• M. F.: C24H54Br2P2Pd2
• M. W.: 777.281082

SYNONYMS

• Title: 三特丁基膦溴化钯
• IUPAC name: bis(bromopalladium); bis(tri-tert-butylphosphane)
• IUPAC Traditional name: bis(bromopalladium); bis(tri-tert-butylphosphane)
• Synonyms: Dibromobis(tri-tert-butylphosphine)dipalladium; 三叔丁基溴化膦钯(I); Dibromobis(tri-tert-butylphosphino)dipalladium(I); Pd-113; [Pd(μ-Br)t-Bu3P]2; Palladium(I) tri-tert-butylphosphine bromide, dimer; 二溴双(三叔丁基膦)化钯

DATABASE IDS

• CAS Number: 185812-86-6
• PubChem SID: 24885391
• MDL Number: MFCD04114019

PROPERTIES

• Linear Formula: [Pd(C4H9)3PBr]2
• GHS Signal Word: Danger
• GHS Hazard statements: H250-H261-H314
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS Precautionary statements: P222-P231 + P232-P280-P305 + P351 + P338-P310-P422
• RID/ADR: UN 3393 4.2/PG 1
• Risk Statements: 14-17-34
• Safety Statements: 26-36/37/39-45
• Storage Temperature: -20°C
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.2
• UN Number: 3393
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Application
Catalyst for C-C, C-N, and N-S bond formation.

• Catalyst for γ-arylation of α,β-unsaturated esters from silyl ketene acetals1 (eq. 1)
• Catalyst for carbon -sulfur bond formation2 (eq. 2)
• Catalyst for diastereoselective arylation of 4-substituted cyclohexyl esters3 (eq. 3)
• Catalyst for Suzuki coupling of hindered aryl bromides4 (eq. 4)
• Catalyst for Buchwald-Hartwig amination reaction of aryl halides4 (eq. 5)
• Catalyst for Negishi coupling reaction5 (eq. 6)
Packaging
1 g in glass bottle

Description (简体中文)

Application
Catalyst for C-C, C-N, and N-S bond formation.

• Catalyst for γ-arylation of α,β-unsaturated esters from silyl ketene acetals1 (eq. 1)
• Catalyst for carbon -sulfur bond formation2 (eq. 2)
• Catalyst for diastereoselective arylation of 4-substituted cyclohexyl esters3 (eq. 3)
• Catalyst for Suzuki coupling of hindered aryl bromides4 (eq. 4)
• Catalyst for Buchwald-Hartwig amination reaction of aryl halides4 (eq. 5)
• Catalyst for Negishi coupling reaction5 (eq. 6)
包装
1 g in glass bottle