(-)-9-(1R,2R-Pseudoephedrinyl)-(10S)-(trimethylsilyl)-9-borabicyclo[3.3.2]decane

• Catalog No.: 676683
• CAS Number: 856676-11-4
• M. F.: C22H38BNOSi
• M. W.: 371.43972

SYNONYMS

• Title: (-)-9-(1R,2R-伪麻黄碱基)-(10S)-(三甲基硅基)-9-硼杂双环[3.3.2]癸烷
• IUPAC name: methyl[(1R,2R)-1-phenyl-1-{[(1R,5s,10S)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]decan-9-yl]oxy}propan-2-yl]amine
• IUPAC Traditional name: methyl[(1R,2R)-1-phenyl-1-{[(1R,5s,10S)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]decan-9-yl]oxy}propan-2-yl]amine

DATABASE IDS

• MDL Number: MFCD09265095
• PubChem SID: 24885324
• CAS Number: 856676-11-4

PROPERTIES

• Empirical Formula (Hill Notation): C22H38BNOSi
• Melting Point: 135-148 °C
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26
• German water hazard class: 3

DETAILS

Description (English)

Application
Air-stable, crystalline pseudoephedrine borinic acid complex which when treated with an appropriate Grignard reagent provides access to homoallylic or homopropargylic alcohols and α-allenyl carbinols.1,2,3
Soderquist Reagents: For allylboration, allenylboration, propargylboration
Packaging
1, 5 g in glass bottle

Description (简体中文)

Application
在空气中稳定的结晶伪麻黄碱硼酸络合物，当用适当的格氏试剂处理后，可与高烯丙醇或高丙炔醇以及 α-联烯基甲醇反应。1,2,3
Soderquist Reagents: For allylboration, allenylboration, propargylboration
包装
1, 5 g in glass bottle