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Triethylborane solution_Molecular_structure_CAS_97-94-9)
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Triethylborane solution

Catalog No. 594377 Name Sigma Aldrich
CAS Number 97-94-9 Website http://www.sigmaaldrich.com
M. F. C6H15B Telephone 1-800-521-8956
M. W. 97.9943 Fax
Purity Email
Storage Chembase ID: 129989

SYNONYMS

Title
三乙基硼 溶液
IUPAC name
triethylborane
IUPAC Traditional name
triethylborane

DATABASE IDS

PubChem SID 24881503
MDL Number MFCD00009022
Beilstein Number 1731462
CAS Number 97-94-9

PROPERTIES

Concentration 2.0 M in diethyl ether
Linear Formula (C2H5)3B
Density 0.703 g/mL at 25 °C
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H250-H302-H314-H336
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P222-P231-P261-P280-P305 + P351 + P338-P422
RID/ADR UN 2845 4.2/PG 1
Risk Statements 17-19-22-34-67
Safety Statements 26-36/37/39-45
Supplemental Hazard Statements May form explosive peroxides.
Hazard Class 4.2
UN Number 2845
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Packaging
100 mL in Sure/Seal™
Application
Catalyst for:
• Allylation of aldehydes1
• Decarboxylative C-C bond cleavage reactions2
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations3
• Regioselective hydroxyalkylation of unsaturated oxime ethers4Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes5Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential6
Description (简体中文)
包装
100 mL in Sure/Seal™
Application
Catalyst for:
• Allylation of aldehydes1
• Decarboxylative C-C bond cleavage reactions2
• Rhenium hydride / boron Lewis acid cocatalysis of alkene hydrogenations3
• Regioselective hydroxyalkylation of unsaturated oxime ethers4Reactant for radical reductions of alkyl bromides with N-heterocyclic carbene boranes5Reactant for synthesis of tetramethylammonium trialkylphenylborate salts with oxidation potential6

REFERENCES