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(+)-α-Tocopherol_Molecular_structure_CAS_59-02-9)
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(+)-α-Tocopherol

Catalog No. T3634 Name Sigma Aldrich
CAS Number 59-02-9 Website http://www.sigmaaldrich.com
M. F. C29H50O2 Telephone 1-800-521-8956
M. W. 430.7061 Fax
Purity Email
Storage Chembase ID: 49

SYNONYMS

IUPAC name
(2R)-2,5,7,8-tetramethyl-2-[(4R,8R)-4,8,12-trimethyltridecyl]-3,4-dihydro-2H-1-benzopyran-6-ol
IUPAC Traditional name
VitaE
Synonyms
D-α-Tocopherol
5,7,8-Trimethyltocol
Vitamin E
2,5,7,8-Tetramethyl-2-(4′,8′,12′-trimethyltridecyl)-6-chromanol

DATABASE IDS

MDL Number MFCD00072045
Beilstein Number 4712525
EC Number 200-412-2
CAS Number 59-02-9
PubChem SID 24900154

PROPERTIES

Biological Source from vegetable oil
Type Type V
Apperance clear yellow to red
Boiling Point 200-220 °C/0.1 mmHg(lit.)
Density 0.95 g/mL at 25 °C(lit.)
Flash Point 110 °C
Flash Point 230 °F
Refractive Index n20/D 1.505(lit.)
Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
RTECS DJ2900000
Storage Temperature -20°C
German water hazard class 1

DETAILS

Description (简体中文)
Caution
Subject to air oxidation.
Other Notes
Mixed isomers
包装
Packaged under argon in a sealed ampule.
Quality
Approx. 670 mg D-α-tocopherol per gram. The non-α content is typically between 5-35 mg/g
Biochem/physiol Actions
Tocopherols (TCP) (vitamin E) are a series (α, β, γ and δ) of chiral organic molecules that vary in their degree of methylation of the phenol moiety of the chromanol ring. Tocopherols are lipid soluble anti-oxidants that protect cell membranes from oxidative damage. α-Tocopherol is the form of tocopherol preferentially absorbed by homo sapiens. Various isofroms and analogues of tocopherol have opposing and differentiated regulatory activities in vivo.
Physical properties
This product is miscible with chloroform or ethanol. It is practically insoluble in water but it is miscible with ether, acetone, and vegetable oils. It is unstable to alkaline conditions.

REFERENCES