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(S,S)-ANDEN-Phenyl Trost Ligand_Molecular_structure_CAS_138517-65-4)
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(S,S)-ANDEN-Phenyl Trost Ligand

Catalog No. 697605 Name Sigma Aldrich
CAS Number 138517-65-4 Website http://www.sigmaaldrich.com
M. F. C54H42N2O2P2 Telephone 1-800-521-8956
M. W. 812.871002 Fax
Purity Email
Storage Chembase ID: 130575

SYNONYMS

Title
(S,S)-ANDEN-苯基 Trost 配体
IUPAC name
2-(diphenylphosphanyl)-N-[(1R,8R,15S,16S)-16-[2-(diphenylphosphanyl)benzamido]tetracyclo[6.6.2.02,7.09,14]hexadeca-2(7),3,5,9(14),10,12-hexaen-15-yl]benzamide
IUPAC Traditional name
2-(diphenylphosphanyl)-N-[(1R,8R,15S,16S)-16-[2-(diphenylphosphanyl)benzamido]tetracyclo[6.6.2.02,7.09,14]hexadeca-2(7),3,5,9(14),10,12-hexaen-15-yl]benzamide
Synonyms
(11S,12S)-N,N′-(9,10-二氢-9,10-乙基桥蒽-11,12-二基)双[2-(二苯基膦)]-苯甲酰胺
(+)-(11S,12S)双[2′-(二苯基膦)苯甲酰氨基]-9,10-二氢-9,10-乙基桥蒽

DATABASE IDS

CAS Number 138517-65-4
MDL Number MFCD12546008

PROPERTIES

Melting Point 123-128 °C
Optical Rotation [α]22/D +111°, c = 1 in chloroform
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (简体中文)
Application
不对称烯丙基烷化反应的配体。1,2,3,4
包装
100, 500 mg in glass bottle
Legal Information
与 Dr. Reddy′s Laboratories 合作销售,仅供研究使用。适用美国专利 5739396。

REFERENCES