silver(1+) ion hexafluorostibanuide

• ChemBase ID: 98967
• Molecular Formular: AgF6Sb
• Molecular Mass: 343.6186192
• Monoisotopic Mass: 341.79933132
• SMILES: [Ag+].[Sb-](F)(F)(F)(F)(F)F
• Canonical SMILES: F[Sb-](F)(F)(F)(F)F.[Ag+]
• InChI: InChI=1S/Ag.6FH.Sb/h;6*1H;/q+1;;;;;;;+5/p-6
• InChIKey: GSXFODUDOAXUBF-UHFFFAOYSA-H

NAMES AND DATABASE IDS

Names

• IUPAC name: silver(1+) ion hexafluorostibanuide
• IUPAC Traditional name: silver(1+) hexafluorostibanuide; silver(1+) ion hexafluorostibanuide
• Synonyms: Silver hexafluoroantimonate(V) 98%; Silver hexafluoroantimonate(V); SILVER HEXAFLUOROANTIMONATE; Silver hexafluoroantimonate; 六氟锑酸银

Database IDs

• CAS Number: 26042-64-8
• EC Number: 247-429-1
• MDL Number: MFCD00003401
• PubChem SID: 162085280; 24853650
• PubChem CID: 16687962

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 2.0606
• LogD (pH = 7.4): 2.0606
• Log P: 2.0606
• Molar Refractivity: 9.0078 cm^3
• Polarizability: 8.143589 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: powder; Powder
• Flash Point: none°C

Safety Information

• Storage Warning: Corrosive/Hygroscopic/Light Sensitive; Light Sensitive & Hygroscopic
• European Hazard Symbols: Corrosive (C); Nature polluting (N); X; Harmful (Xn)
• UN Number: 3260; UN3260
• German water hazard class: 2
• Hazard Class: 8
• Packing Group: 2; III
• Risk Statements: 20/22-34-51/53; 20/22-51/53
• Safety Statements: 26-36/37/39-45-61; 61
• TSCA Listed: 是
• GHS Pictograms: GHS05; GHS07; GHS09
• GHS Signal Word: Warning
• GHS Hazard statements: H302-H332-H411; H314-H302-H332-H411
• GHS Precautionary statements: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A; P273
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• RID/ADR: UN 3260 8/PG 2

Product Information

• Purity: 98%; 99%
• Linear Formula: AgSbF6

DETAILS

MP Biomedicals - 05217678

MP Biomedicals Rare Chemical collection

Apollo Scientific Ltd - PC6390

Lewis acid catalyst for electrophilic halogenation of alkenes, can also promote rearrangements of 3-bromoflavanones to isoflavanones, ask for references

Sigma Aldrich - 227730

Packaging
1, 5, 25 g in amber poly
Application
Generates stable cation radical salts1,2 and is used as an acidic catalyst in epoxide opening reactions3 and sulfenylation reactions.4 Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials.5

REFERENCES

• Lewis acid catalyst. Catalyst for electrophilic halogenation of alkanes: J. Am. Chem. Soc., 95, 7680, 7686 (1973). See also Antimony(V) fluoride, 33484.
• Promotes rearrangement of 3-bromoflavanones to isoflavones: J. Chem. Soc., Chem. Commun., 151 (1976); and remote hydroxylation of ɑ-bromo keto steroids: J. Org. Chem., 47, 4268 (1982).