NAMES AND DATABASE IDS
NAMES AND DATABASE IDS
Names Database IDs
IUPAC name
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iminooxidanium; tetrafluoroboranuide
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IUPAC Traditional name
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nitrosonium tetrafluoroborate
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Synonyms
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Nitrosyl tetrafluoroborate
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Nitrosonium tetrafluoroborate 98%
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Nitrosonium tetrafluoroborate
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Nitrosyl tetrafluoroborate
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Nitrosonium tetrafluoroborate
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四氟硼酸亚硝
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亚硝四氟硼酸盐
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四氟硼酸亚硝鎓
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CAS Number
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EC Number
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MDL Number
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Merck Index
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PubChem SID
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PubChem CID
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DATA SOURCES
DATA SOURCES
All Sources Commercial Sources Non-commercial Sources
CALCULATED PROPERTIES
CALCULATED PROPERTIES
JChem
H Acceptors
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0
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H Donor
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0
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LogD (pH = 5.5)
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-1.13
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LogD (pH = 7.4)
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-1.13
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Log P
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-1.13
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Molar Refractivity
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6.0052 cm3
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Polarizability
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3.1085358 Å3
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Polar Surface Area
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0.0 Å2
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Rotatable Bonds
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0
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Lipinski's Rule of Five
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true
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DETAILS
DETAILS
Apollo Scientific
Sigma Aldrich
Apollo Scientific Ltd -
PC5290
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Versatile crystalline nitrosating agent. Converts arylamines to aryl fluorides via diazonium tetrafluoroborates: Chem. Ber., 88, 1939 (1995).. in Teflon bottles |
REFERENCES
REFERENCES
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PubMed
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- • Undergoes an interesting insertion reaction with diarylcyclopropanes: Chem. Lett., 233 (1988):
- • With excess reagent, oxidation of the isoxazoline to the isoxazole occurs.
- • Crystalline nitrosating agent: Secondary amines to nitrosamines: Chem. Ber., 89, 2374 (1956); deamination of primary amides: J. Org. Chem., 30, 2386 (1965); conversion of arylhydrazines to azides: Tetrahedron Lett., 28, 5091 (1987). In organic solvents, converts arylamines directly to diazonium tetrafluoroborates which undergo the Balz-Schiemann reaction (see Tetrafluoroboric acid, L14037) in situ to give high yields of aryl fluorides: Chem. Ber., 88, 1939 (1955); EP 430,434 (1991). Methyl or methoxy substituted aromatics in acetonitrile give the nitrosoaromatics in good yield: J. Org. Chem., 59, 5573 (1994).
- • Convenient catalyst for iodination of aromatics by iodide ion with air as oxidant: J. Org. Chem., 53, 3548 (1988), or for addition of iodine (or iodine + nucleophile) to alkenes: Acta Chem. Scand. B, 43, 902 (1989).
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PATENTS
PATENTS
PubChem Patent
Google Patent