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14104-20-2 molecular structure
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silver(1+) ion tetrafluoroboranuide

ChemBase ID: 9804
Molecular Formular: AgBF4
Molecular Mass: 194.6728128
Monoisotopic Mass: 193.90801528
SMILES and InChIs

SMILES:
F[B-](F)(F)F.[Ag+]
Canonical SMILES:
F[B-](F)(F)F.[Ag+]
InChI:
InChI=1S/Ag.BF4/c;2-1(3,4)5/q+1;-1
InChIKey:
CCAVYRRHZLAMDJ-UHFFFAOYSA-N

Cite this record

CBID:9804 http://www.chembase.cn/molecule-9804.html

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NAMES AND DATABASE IDS

NAMES AND DATABASE IDS

Names Database IDs
IUPAC name
silver(1+) ion tetrafluoroboranuide
IUPAC Traditional name
silver(1+) tetrafluoroborate
silver(1+) ion tetrafluoroborate
Synonyms
Silver tetrafluoroborate 99%
Silver tetrafluoroborate
Silver borofluoride
Silver tetrafluoroborate
Borate(1-)
tetrafluoro)
silver(1+)
Tetrafluoroboric acid silver salt
氟硼酸银
四氟硼酸银
CAS Number
14104-20-2
EC Number
237-956-5
MDL Number
MFCD00003408
PubChem SID
160973111
24852510
24871863
PubChem CID
159722
Chemspider ID
140438
Wikipedia Title
Silver_tetrafluoroborate

CALCULATED PROPERTIES

CALCULATED PROPERTIES

JChem
H Acceptors H Donor
LogD (pH = 5.5) -1.13  LogD (pH = 7.4) -1.13 
Log P -1.13  Molar Refractivity 6.0052 cm3
Polarizability 3.1085358 Å3 Polar Surface Area 0.0 Å2
Rotatable Bonds Lipinski's Rule of Five true 

PROPERTIES

PROPERTIES

Physical Property Safety Information Product Information Bioassay(PubChem)
Solubility
soluble in water expand Show data source
Apperance
Crystalline expand Show data source
Off-white powder expand Show data source
powder expand Show data source
Melting Point
200°C expand Show data source
200°C dec. expand Show data source
70-73 °C(lit.) expand Show data source
70-73°C expand Show data source
71.5°C expand Show data source
Storage Warning
Corrosive/Harmful/Light Sensitive/Moisture Sensitive/Store under Argon expand Show data source
Light Sensitive & Hygroscopic expand Show data source
MOISTURE SENSITIVE, CORROSIVE expand Show data source
RTECS
ED2875000 expand Show data source
European Hazard Symbols
Corrosive Corrosive (C) expand Show data source
X expand Show data source
UN Number
3260 expand Show data source
UN3260 expand Show data source
MSDS Link
Download expand Show data source
Download expand Show data source
Download expand Show data source
German water hazard class
3 expand Show data source
Hazard Class
8 expand Show data source
Packing Group
2 expand Show data source
II expand Show data source
Risk Statements
22-34 expand Show data source
34 expand Show data source
Safety Statements
26-36/37/39-45 expand Show data source
26-36/37/39-45-60 expand Show data source
TSCA Listed
true expand Show data source
expand Show data source
GHS Pictograms
GHS05 expand Show data source
GHS06 expand Show data source
GHS Signal Word
Danger expand Show data source
NFPA704
NFPA 704 diagram
0
3
0
expand Show data source
GHS Hazard statements
H301-H314-H318 expand Show data source
H314 expand Show data source
GHS Precautionary statements
P280-P303+P361+P353-P305+P351+P338-P310 expand Show data source
P280-P305 + P351 + P338-P310 expand Show data source
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges expand Show data source
RID/ADR
UN 3260 8/PG 2 expand Show data source
Purity
≥99.99% trace metals basis expand Show data source
98% expand Show data source
99% expand Show data source
Linear Formula
AgBF4 expand Show data source

DETAILS

DETAILS

Apollo Scientific Apollo Scientific Wikipedia Wikipedia Sigma Aldrich Sigma Aldrich
Apollo Scientific Ltd - PC6430 external link
Converts alpha-bromoalkanones to the corresponding fluoro-derivative, Tetrahedron Lett., 1979, 3357.Soluble in many organic solvents.
Sigma Aldrich - 208361 external link
Packaging
1, 10, 50 g in amber poly
Application
Gold Catalysts - 21st Century ′Gold Rush′
Sigma Aldrich - 483052 external link
Packaging
5, 25 g in amber poly

REFERENCES

REFERENCES

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  • • Silver salt soluble in many organic solvents; useful, e.g. in promotion of the leaving ability of halogens. Promotes the conversion of ɑ-bromo aldehydes and ketones to their ɑ-fluoro equivalents: Tetrahedron Lett., 3357 (1979).
  • • For use in the preparation of stable, non-hygroscopic, crystalline acylammonium salts, see: J. Org. Chem., 57, 5136 (1992).
  • • In the presence of AgBF4, acetals of phenacyl halides undergo rearrangement to esters of arylacetic acids: J. Chem. Soc., Perkin 1, 2575 (1982); compare Silver nitrate, 11414.
  • • Mediates the oxidative coupling of silylated cyclopropanols to 1,6-diones: J. Am. Chem. Soc., 105, 7192 (1983):
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PATENTS

PATENTS

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INTERNET

INTERNET

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