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14283-07-9 molecular structure
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lithium(1+) ion tetrafluoroboranuide

ChemBase ID: 98036
Molecular Formular: BF4Li
Molecular Mass: 93.7456128
Monoisotopic Mass: 94.01892283
SMILES and InChIs

SMILES:
[Li+].[B-](F)(F)(F)F
Canonical SMILES:
F[B-](F)(F)F.[Li+]
InChI:
InChI=1S/BF4.Li/c2-1(3,4)5;/q-1;+1
InChIKey:
UFXJWFBILHTTET-UHFFFAOYSA-N

Cite this record

CBID:98036 http://www.chembase.cn/molecule-98036.html

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NAMES AND DATABASE IDS

NAMES AND DATABASE IDS

Names Database IDs
IUPAC name
lithium(1+) ion tetrafluoroboranuide
IUPAC Traditional name
lithium(1+) ion tetrafluoroborate
LithoTab tetrafluoroborate
Synonyms
LITHIUM TETRA FLUOROBORATE
Lithium tetrafluoroborate solution
Lithium borofluoride
Lithium fluoroborate
Lithium tetrafluoroborate
Lithium tetrafluoroborate, ultra dry
Borate(1-)
tetrafluoro)
lithium
Lithium tetrafluoroborate
Lithium tetrafluoroborate, anhydrous 98%
四氟硼酸锂 溶液
氟硼酸锂
四氟硼酸锂
四氟硼酸锂,超干
CAS Number
14283-07-9
EC Number
238-178-9
MDL Number
MFCD00011087
Merck Index
145543
PubChem SID
24855484
162084502
24854701
24868639
PubChem CID
4298216
Chemspider ID
3504162
Wikipedia Title
Lithium_tetrafluoroborate

CALCULATED PROPERTIES

CALCULATED PROPERTIES

JChem
H Acceptors H Donor
LogD (pH = 5.5) -1.13  LogD (pH = 7.4) -1.13 
Log P -1.13  Molar Refractivity 6.0052 cm3
Polarizability 3.1085358 Å3 Polar Surface Area 0.0 Å2
Rotatable Bonds Lipinski's Rule of Five true 

PROPERTIES

PROPERTIES

Physical Property Safety Information Product Information Bioassay(PubChem)
Solubility
Very soluble in water expand Show data source
Apperance
liquid expand Show data source
powder expand Show data source
Powder expand Show data source
Powder, Ampouled under argon expand Show data source
White/grey crystalline solid expand Show data source
Melting Point
293-300 °C (dec.)(lit.) expand Show data source
293-300°C dec. expand Show data source
296.5 °C expand Show data source
309-311°C expand Show data source
Boiling Point
decomp expand Show data source
Flash Point
42 °F expand Show data source
6 °C expand Show data source
Density
0.852 g/cm3 solid expand Show data source
0.852 g/mL at 25 °C expand Show data source
Odor
odorless expand Show data source
Storage Warning
Corrosive/Hygroscopic expand Show data source
Hygroscopic expand Show data source
European Hazard Symbols
Corrosive Corrosive (C) expand Show data source
Flammable Flammable (F) expand Show data source
Toxic Toxic (T) expand Show data source
X expand Show data source
UN Number
1992 expand Show data source
3260 expand Show data source
UN3260 expand Show data source
MSDS Link
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
German water hazard class
3 expand Show data source
Hazard Class
3 expand Show data source
8 expand Show data source
Packing Group
2 expand Show data source
III expand Show data source
Risk Statements
11-23/24/25-36/37/38 expand Show data source
20/21/22-31-34 expand Show data source
21/22-34 expand Show data source
R:14/15-34 expand Show data source
Safety Statements
16-26-27-36/37/39-45 expand Show data source
22-26-27-36/37/39-45 expand Show data source
26-36/37/39-45 expand Show data source
S:8-45 expand Show data source
TSCA Listed
expand Show data source
GHS Pictograms
GHS05 expand Show data source
GHS06 expand Show data source
GHS07 expand Show data source
GHS Signal Word
Danger expand Show data source
Main Hazard
Harmful, causes burns,
hygroscopic.
expand Show data source
NFPA704
NFPA 704 diagram
0
1
1
expand Show data source
GHS Hazard statements
H301-H311-H314-H318 expand Show data source
H302 + H312 + H332-H314 expand Show data source
GHS Precautionary statements
P260-P301+P310-P303+P361+P353-P305+P351+P338-P361-P405-P501A expand Show data source
P280-P305 + P351 + P338-P310 expand Show data source
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges expand Show data source
RID/ADR
UN 1992 3/PG 2 expand Show data source
UN 3260 8/PG 2 expand Show data source
Purity
98% expand Show data source
99.997% (metals basis) expand Show data source
99.998% trace metals basis expand Show data source
Concentration
1.0 M in acetonitrile expand Show data source
Grade
anhydrous expand Show data source
Certificate of Analysis
Download expand Show data source
Linear Formula
LiBF4 expand Show data source

DETAILS

DETAILS

MP Biomedicals MP Biomedicals Apollo Scientific Apollo Scientific Wikipedia Wikipedia Sigma Aldrich Sigma Aldrich
MP Biomedicals - 05221088 external link
MP Biomedicals Rare Chemical collection
Apollo Scientific Ltd - PC5010 external link
Tetrahedron Lett., 21, 35 (1980): Reagent for cleavage of TBDMS ethers in MeCN-CH2Cl2. In dry MeCN is useful for the cleavage of 2-(TMS)ethyl protected glycosides.
Sigma Aldrich - 451622 external link
Packaging
5, 25 g in ampule
Application
Used recently in the development of a solid composite electrolyte for lithium batteries.1
Sigma Aldrich - 255815 external link
Packaging
100 mL in Sure/Seal™
Sigma Aldrich - 244767 external link
Packaging
10, 50 g in glass bottle
Application
Mild Lewis acid for Diels-Alder reactions.1 Catalyst for mild and efficient aminolysis of oxiranes.2

REFERENCES

REFERENCES

From Suppliers Google Scholar IconGoogle Scholar PubMed iconPubMed Google Books IconGoogle Books
  • • Reagent for cleavage of tert-butyldimethylsilyl ethers in MeCN/CH2Cl2: Tetrahedron Lett., 21, 35 (1980). In dry acetonitrile, it is useful for the cleavage of 2-(TMS)ethyl protected glycosides: Tetrahedron Lett., 22, 4603 (1981). Catalyzes the regioselective azidolysis of epoxides with sodium azide in wet tert-butanol: Synth. Commun., 33, 999 (2003). Formation of THP ethers from alcohols is catalyzed by LiBF4 in acetonitrile: Synlett, 1261 (1999).
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PATENTS

PATENTS

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INTERNET

INTERNET

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