pentachloro-λ5-phosphane

• ChemBase ID: 89580
• Molecular Formular: Cl5P
• Molecular Mass: 208.238761
• Monoisotopic Mass: 205.81802503
• SMILES: P(Cl)(Cl)(Cl)(Cl)Cl
• Canonical SMILES: ClP(Cl)(Cl)(Cl)Cl
• InChI: InChI=1S/Cl5P/c1-6(2,3,4)5
• InChIKey: UHZYTMXLRWXGPK-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: pentachloro-λ^5-phosphane; pentachloro-$l^{5}-phosphane
• IUPAC Traditional name: pentachloro-λ^5-phosphane; phosphorus pentachloride
• Synonyms: Phosphorus pentachloride; Phosphorus pentachloride; Phosphorus(V) chloride, polymer-bound; Phosphorus pentachloride, polymer-bound; Pentachlorophosphorane; Phosphorus(V) chloride; Phosphorus pentachloride 98+%; Phosphorus(V) chloride; 氯化磷(V); 五氯化磷; 聚合物键合型氯化磷(V); 聚合物键合型五氯化磷; 氯化磷(V)

Database IDs

• CAS Number: 10026-13-8
• EC Number: 233-060-3
• MDL Number: MFCD00011439
• Merck Index: 147351
• PubChem SID: 24883291; 162076455; 24849700
• PubChem CID: 24819
• Wikipedia Title: Phosphorus_pentachloride

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 3.4725
• LogD (pH = 7.4): 3.4725
• Log P: 3.4725
• Molar Refractivity: 35.8815 cm^3
• Polarizability: 14.072733 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: decomposition; (exothermic) in water; Soluble in carbon disulfide and carbon tetrachloride; soluble in CS₂, chlorocarbons, benzene
• Apperance: colourless crystals; macroporous; Solid
• Melting Point: 162°C subl.; 166.8 °C, 440.0 K, 332.2 °F; 179-181 °C (subl.)(lit.); 179-181(subl.)°C
• Boiling Point: 160.5°C (sublimation)
• Flash Point: Non-flammable
• Density: 2.1 g/cm^3; 2.114
• Vapor Pressure: <1 mmHg ( 20 °C)

Safety Information

• Storage Warning: Moisture Sensitive; Very Toxic/Corrosive/Harmful/Moisture Sensitive/Store under Argon
• RTECS: TB6125000
• European Hazard Symbols: Highly toxic (T+)
• UN Number: 1806; UN1806
• German water hazard class: 1; 3
• Hazard Class: 8
• Packing Group: 2; II
• Risk Statements: 14-22-26-29-34-48/20; 14-22-26-34-48/20; R14, R22, R26, R34, R48/20
• Safety Statements: 7/8-26-36/37/39-45; S1/2, S7/8, S26, S36/37/39, S45
• TSCA Listed: 是
• EU Index: 015-008-00-X
• GHS Pictograms: GHS05; GHS06; GHS08
• GHS Signal Word: Danger
• NFPA704:
  

  0

  3

  2

  W
• LD50: 660 mg/kg
• GHS Hazard statements: H302-H314-H330-H373; H330-H302-H314-H373
• GHS Precautionary statements: P260-P280-P284-P305 + P351 + P338-P310; P260-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501A
• Personal Protective Equipment: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges; Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• RID/ADR: UN 1806 8/PG 2
• Supplemental Hazard Statements: Reacts violently with water.
• Storage Temperature: 2-8°C

Product Information

• Purity: 95%; 98%; 99.998% (metals basis)
• Grade: CP; reagent grade
• Particle Size: 16-50 mesh
• Extent of Labeling: 1.0-1.5 mmol/g loading
• Linear Formula: PCl5

DETAILS

Sigma Aldrich - 643726

Packaging
25 g in glass bottle

Sigma Aldrich - 157775

Packaging
1 kg in glass bottle
5, 100 g in glass bottle