gold(1+) ion chloride

• ChemBase ID: 303513
• Molecular Formular: AuCl
• Molecular Mass: 232.41955
• Monoisotopic Mass: 231.93542068
• SMILES: [Cl-].[Au+]
• Canonical SMILES: [Cl-].[Au+]
• InChI: InChI=1S/Au.ClH/h;1H/q+1;/p-1
• InChIKey: FDWREHZXQUYJFJ-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: gold(1+) ion chloride
• IUPAC Traditional name: gold(1+) ion chloride
• Synonyms: Gold(I) chloride; Gold(I) chloride, Premion®; 氯化亚金(I); 氯化亚金(I), Premion®

Database IDs

• CAS Number: 10294-29-8
• EC Number: 233-655-8
• MDL Number: MFCD00046175
• Merck Index: 144515

CALCULATED PROPERTIES

• Acid pKa: -7.0
• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 0.8327582
• LogD (pH = 7.4): 0.8327582
• Log P: 0.6123387
• Molar Refractivity: 5.6156 cm^3
• Polarizability: 2.1090326 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: Powder
• Melting Point: 289°C dec.
• Density: 7.57

Safety Information

• Storage Warning: Moisture Sensitive
• European Hazard Symbols: Corrosive (C)
• UN Number: UN3260
• Hazard Class: 8
• Packing Group: III
• Risk Statements: 34
• Safety Statements: 20-26-36/37/39-45
• TSCA Listed: 是
• GHS Pictograms: GHS05
• GHS Hazard statements: H314-H318
• GHS Precautionary statements: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A

Product Information

• Purity: 99.9% (metals basis); 99.99% (metals basis), Au 84.2% min

REFERENCES

• Catalyzes the rapid cyclization of allenyl and propargyl ketones to 2,5-disubstituted furans. Also useful in the Michael addition of methyl vinyl ketone to 2-methylfuran in acetonitrile: Agnew. Chem. Int. Ed.,39, 2285 (2000). For use in the gold-cataylzed amination of allylic alcohols with arylamines and arylsulfonamides, see: Synlett, 964 (2007).