palladium(2+) ion disodium tetrachloride

• ChemBase ID: 302853
• Molecular Formular: Cl4Na2Pd
• Molecular Mass: 294.21154
• Monoisotopic Mass: 291.75843528
• SMILES: [Na+].[Na+].[Cl-].[Cl-].[Cl-].[Cl-].[Pd+2]
• Canonical SMILES: [Na+].[Na+].[Cl-].[Cl-].[Cl-].[Cl-].[Pd+2]
• InChI: InChI=1S/4ClH.2Na.Pd/h4*1H;;;/q;;;;2*+1;+2/p-4
• InChIKey: ZIXLZKBNIAXVBE-UHFFFAOYSA-J

NAMES AND DATABASE IDS

Names

• IUPAC name: palladium(2+) ion disodium tetrachloride
• IUPAC Traditional name: palladium(2+) ion disodium tetrachloride
• Synonyms: Sodium chloropalladate(II); Palladium sodium chloride; Sodium tetrachloropalladate(II) hydrate; 四氯钯酸钠水合物

Database IDs

• CAS Number: 13820-53-6
• EC Number: 237-502-6
• MDL Number: MFCD00003487

CALCULATED PROPERTIES

• Acid pKa: 3.09
• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): -0.77
• LogD (pH = 7.4): -0.77
• Log P: -0.77
• Molar Refractivity: 0.0 cm^3
• Polarizability: 2.0172503 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: Crystalline

Safety Information

• Storage Warning: Hygroscopic
• RTECS: RT3480000
• European Hazard Symbols: X
• Risk Statements: 22-41
• Safety Statements: 26-36/39-60
• TSCA Listed: 是
• GHS Pictograms: GHS05; GHS07
• GHS Hazard statements: H318-H290-H302
• GHS Precautionary statements: P280F-P305+P351+P338

Product Information

• Purity: 99.95% (metals basis), Pd 30%

REFERENCES

• For use as a catalyst in the carbonylation of allylic halides to give ?-unsaturated esters, see: Chem. Lett., 1873 (1989).
• In the presence of CsF in aqueous MeOH, catalyzes the cross-coupling of aryl boronates with aryldiazonium salts to give biaryls; no reaction occurs in anhydrous solvents: Tetrahedron Lett., 41, 6271 (2000).