NAMES AND DATABASE IDS
NAMES AND DATABASE IDS
Names Database IDs
IUPAC name
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disodium tetrahydroxy-1,2,4,5,3,6-tetraoxadiborinane-3,6-diuide hexahydrate
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IUPAC Traditional name
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disodium hexahydrate perborate
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Synonyms
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Sodium perborate tetrahydrate
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过硼酸钠四水合物
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CAS Number
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EC Number
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MDL Number
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Merck Index
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PubChem SID
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PubChem CID
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DATA SOURCES
DATA SOURCES
All Sources Commercial Sources Non-commercial Sources
CALCULATED PROPERTIES
CALCULATED PROPERTIES
JChem
H Acceptors
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8
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H Donor
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4
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LogD (pH = 5.5)
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-6.06
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LogD (pH = 7.4)
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-6.06
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Log P
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-6.06
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Molar Refractivity
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15.6592 cm3
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Polarizability
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10.538063 Å3
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Polar Surface Area
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117.84 Å2
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Rotatable Bonds
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0
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Lipinski's Rule of Five
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true
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REFERENCES
REFERENCES
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- • In combination with triflic acid for hydroxylation of aromatics: Synlett, 39 (1991).
- • In combination with acetic anhydride, cyclic acetals are cleaved to their respective esters: Synlett., 329 (1995).
- • For phase-transfer oxidation of alcohols to ketones, catalyzed by Chromium(VI) oxide, 12522, see: Synth. Commun., 21, 575 (1991).
- • For a brief feature on uses in synthesis, see: Synlett, 2513 (2006).
- • Useful, inexpensive oxidant. Reviews: Chemtech, 566 (1991); Tetrahedron, 51, 6145 (1995); Synthesis, 1325 (1995); J. Chem. Soc., Perkin 1, 471 (2000). Examples: Oxidation of secondary alcohols to ketones, and ɑ-hydroxy acids to keto acids: Synthesis, 765 (1989). Mild epoxidation of ɑ?-unsaturated ketones: Synth. Commun., 19, 3579 (1989); Tetrahedron Lett., 36, 663 (1995). Partial hydrolysis of nitriles to amides: Tetrahedron, 45, 3299 (1989); Synth. Commun., 20, 563 (1990). Oxidation (in AcOH) of sulfides to sulfoxides or sulfones, arylamines to nitro compounds, and Baeyer-Villiger oxidation of ketones to esters: Tetrahedron, 43, 1753 (1987). Oxidation (in AcOH) of aromatic aldehydes to acids: Tetrahedron, 45, 3299 (1989); or oximes to nitro compounds: Synlett, 337 (1992). Oxidative conversion of organoboranes to alcohols: Org. Synth. Coll., 9, 522 (1998).
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PATENTS
PATENTS
PubChem Patent
Google Patent