tetraethylazanium periodate

• ChemBase ID: 152744
• Molecular Formular: C8H20INO4
• Molecular Mass: 321.15317
• Monoisotopic Mass: 321.04370613
• SMILES: CC[N+](CC)(CC)CC.[O-][I](=O)(=O)=O
• Canonical SMILES: [O-][I](=O)(=O)=O.CC[N+](CC)(CC)CC
• InChI: InChI=1S/C8H20N.HIO4/c1-5-9(6-2,7-3)8-4;2-1(3,4)5/h5-8H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
• InChIKey: YXYPONURGKGPDV-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: tetraethylazanium periodate
• IUPAC Traditional name: tetraethylammonium periodate
• Synonyms: N,N,N-Triethylethanaminium salt with periodic acid; Tetraethylammonium (meta)periodate; 四乙基高碘酸铵

Database IDs

• CAS Number: 5492-69-3
• EC Number: 226-824-2
• MDL Number: MFCD00043182
• Beilstein Number: 4166132
• PubChem SID: 162246887; 24888418
• PubChem CID: 3014363

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): -2.5449352
• LogD (pH = 7.4): -2.5449352
• Log P: -2.5449352
• Molar Refractivity: 54.8961 cm^3
• Polarizability: 16.958946 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 4
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Melting Point: ~170 °C (dec.)

Safety Information

• European Hazard Symbols: Flammable (F)
• UN Number: 1325
• German water hazard class: 3
• Hazard Class: 4.1
• Packing Group: 2
• Risk Statements: 11
• Safety Statements: 16
• GHS Pictograms: GHS02
• GHS Signal Word: Danger
• GHS Hazard statements: H228
• GHS Precautionary statements: P210
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• RID/ADR: UN 1325 4.1/PG 2

Product Information

• Purity: ≥90% (calc. based on dry substance, RT)
• Grade: technical
• Contains: ~10% water as stabilizer
• Quality: moistened with water
• Linear Formula: (C2H5)4N(IO4)

DETAILS

Sigma Aldrich - 86652

Other Notes
Oxidant for use in organic solvents2,3; Oxidation of 1,2-diols and olefins 4
Packaging
10 g in glass bottle
Application
Reactant for intramolecular cycloaddition reactions1