tetrapropylazanium periodate

• ChemBase ID: 152416
• Molecular Formular: C12H28INO4
• Molecular Mass: 377.25949
• Monoisotopic Mass: 377.10630638
• SMILES: CCC[N+](CCC)(CCC)CCC.[O-][I](=O)(=O)=O
• Canonical SMILES: [O-][I](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC
• InChI: InChI=1S/C12H28N.HIO4/c1-5-9-13(10-6-2,11-7-3)12-8-4;2-1(3,4)5/h5-12H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
• InChIKey: HDTMHCZUXQKRAJ-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: tetrapropylazanium periodate
• IUPAC Traditional name: tetrapropylammonium periodate
• Synonyms: Tetrapropylammonium (meta)periodate; 四丙基高碘酸铵

Database IDs

• CAS Number: 85169-30-8
• EC Number: 285-973-1
• MDL Number: MFCD00043184
• PubChem SID: 162246561; 24889059
• PubChem CID: 3020483

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): -0.45484576
• LogD (pH = 7.4): -0.45484576
• Log P: -0.45484576
• Molar Refractivity: 72.9921 cm^3
• Polarizability: 24.346558 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 8
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Melting Point: 181-183 °C (dec.)(lit.)

Safety Information

• European Hazard Symbols: Oxidising (O); Irritant (Xi)
• UN Number: 1325
• German water hazard class: 3
• Hazard Class: 4.1
• Packing Group: 2
• Risk Statements: 1-8-36/37/38
• Safety Statements: 17-26
• GHS Pictograms: GHS02; GHS03; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H228-H272-H315-H319-H335
• GHS Precautionary statements: P210-P220-P261-P305 + P351 + P338
• Personal Protective Equipment: Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1325 4.1/PG 2
• Supplemental Hazard Statements: Explosive when dry.

Product Information

• Purity: ≥98.0% (calc. based on dry substance, RT)
• Contains: ~10% water as stabilizer
• Quality: moistened with water
• Linear Formula: (CH3CH2CH2)4N(IO4)

DETAILS

Sigma Aldrich - 88125

Other Notes
Oxidation reagent, soluble in organic solvents2,3,4
Packaging
5 g in glass bottle
Application
Reagent for:
• Preparation of acylnitroso compoubnds used in Diels-Alder reactions1