trichloro(ethenyl)silane

• ChemBase ID: 150008
• Molecular Formular: C2H3Cl3Si
• Molecular Mass: 161.48972
• Monoisotopic Mass: 159.90695967
• SMILES: C=C[Si](Cl)(Cl)Cl
• Canonical SMILES: C=C[Si](Cl)(Cl)Cl
• InChI: InChI=1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2
• InChIKey: GQIUQDDJKHLHTB-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: trichloro(ethenyl)silane
• IUPAC Traditional name: vinyltrichlorosilane
• Synonyms: (Trichlorosilyl)ethylene; Vinyltrichlorosilane; Trichlorovinylsilane; Trichlorovinylsilane; Vinyltrichlorosilane; 三氯硅烷基乙烯; 乙烯三氯化硅; 乙烯基三氯硅烷; 三氯乙烯硅烷

Database IDs

• CAS Number: 75-94-5
• EC Number: 200-917-8
• MDL Number: MFCD00000482
• Beilstein Number: 1743440
• PubChem SID: 162244170; 24890091; 24846680
• PubChem CID: 6413

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 2.4796
• LogD (pH = 7.4): 2.4796
• Log P: 2.4796
• Molar Refractivity: 27.8912 cm^3
• Polarizability: 12.796337 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 1
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Melting Point: -95 °C(lit.); -95°C
• Boiling Point: 90 °C(lit.); 91-93°C
• Flash Point: 10 °C; 10°C(50°F); 50 °F
• Density: 1.27 g/mL at 25 °C(lit.); 1.270
• Refractive Index: 1.4360; n20/D 1.435; n20/D 1.436(lit.)
• Vapor Pressure: 60 mmHg ( 23 °C)
• Vapor Density: >1 (vs air)

Safety Information

• Storage Warning: Moisture Sensitive
• RTECS: VV6125000
• European Hazard Symbols: Corrosive (C); Flammable (F); X
• UN Number: 1305; UN1305
• German water hazard class: 3
• Hazard Class: 3
• Packing Group: 1; II
• Risk Statements: 11-14-20/21/22-34
• Safety Statements: 16-23-26-30-33-36/37/39-45; 16-26-36/37/39-45
• TSCA Listed: 是
• GHS Pictograms: GHS02; GHS05; GHS06
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H302 + H332-H311-H314; H225-H311-H302-H332-H314-H318
• GHS Precautionary statements: P210-P280-P305 + P351 + P338-P310; P210-P303+P361+P353-P305+P351+P338-P361-P405-P501A
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 1305 3/PG 1
• Supplemental Hazard Statements: Reacts violently with water.
• Storage Temperature: 2-8°C

Product Information

• Purity: ≥97.0% (GC); 97%
• Grade: technical
• Linear Formula: H2C=CHSiCl3

DETAILS

Sigma Aldrich - 104876

Packaging
100, 500 g in glass bottle

REFERENCES

• Undergoes the ene (insertion) reaction with suitable alkenes: Compt. Rend., 278(C), 375 (1974).