ethene bis(triphenylphosphane) platinum

• ChemBase ID: 149669
• Molecular Formular: C38H34P2Pt
• Molecular Mass: 747.702082
• Monoisotopic Mass: 747.17836535
• SMILES: C=C.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.[Pt]
• Canonical SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.C=C.[Pt]
• InChI: InChI=1S/2C18H15P.C2H4.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;/h2*1-15H;1-2H2
• InChIKey: RZUASTIKPBCXPU-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: ethene bis(triphenylphosphane) platinum
• IUPAC Traditional name: ethylene bis(triphenylphosphine) platinum
• Synonyms: Ethylenebis(triphenylphosphine)platinum(0); 乙烯双(三苯基磷)铂

Database IDs

• CAS Number: 12120-15-9
• MDL Number: MFCD00012028
• PubChem SID: 162243832; 24855778
• PubChem CID: 2734701

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 5.1066
• LogD (pH = 7.4): 5.1066
• Log P: 5.1066
• Molar Refractivity: 81.6229 cm^3
• Polarizability: 32.34495 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 6
• Lipinski's Rule of Five: false

PROPERTIES

Physical Property

• Melting Point: 129-132 °C (dec.)(lit.)

Safety Information

• European Hazard Symbols: Irritant (Xi)
• German water hazard class: 3
• Risk Statements: 36/37/38
• Safety Statements: 26-37/39
• GHS Pictograms: GHS07
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• GHS Precautionary statements: P261-P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves

Product Information

• Linear Formula: [(C6H5)3P]2Pt(H2C=CH2)

DETAILS

Sigma Aldrich - 260916

Application
Nucleophilic metal species for ligand exchangewith alkenes and alkynes; catalysts for hydrosilation; reagent for oxidative addition to activated C-X bonds
Packaging
1 g in glass bottle