dichloropalladium diamine

• ChemBase ID: 149388
• Molecular Formular: Cl2H6N2Pd
• Molecular Mass: 211.38704
• Monoisotopic Mass: 209.89428956
• SMILES: N.N.Cl[Pd]Cl
• Canonical SMILES: Cl[Pd]Cl.N.N
• InChI: InChI=1S/2ClH.2H3N.Pd/h2*1H;2*1H3;/q;;;;+2/p-2
• InChIKey: WIEZTXFTOIBIOC-UHFFFAOYSA-L

NAMES AND DATABASE IDS

Names

• IUPAC name: dichloropalladium diamine
• IUPAC Traditional name: palladium chloride diamine
• Synonyms: trans-Bisamminedichloropalladium; Transpalladin; trans-Diamminedichloropalladium(II); 反-二氨基二氯化钯

Database IDs

• CAS Number: 13782-33-7
• EC Number: 237-437-3
• MDL Number: MFCD00011621
• PubChem SID: 162243554; 24852080
• PubChem CID: 61732

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.269
• LogD (pH = 7.4): 1.269
• Log P: 1.269
• Molar Refractivity: 12.2726 cm^3
• Polarizability: 9.574385 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Density: 2.5 g/mL at 25 °C(lit.)

Safety Information

• European Hazard Symbols: Toxic (T)
• German water hazard class: 3
• Risk Statements: 23/24/25-36/37/38
• Safety Statements: 22-26-36/37/39-45
• GHS Pictograms: GHS06
• GHS Signal Word: Danger
• GHS Hazard statements: H301-H311-H315-H319-H331-H335
• GHS Precautionary statements: P261-P280-P301 + P310-P305 + P351 + P338-P311
• Personal Protective Equipment: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Product Information

• Purity: 99.998%
• Linear Formula: Pd(NH3)2Cl2

DETAILS

Sigma Aldrich - 203955

Packaging
1 g in glass bottle
Application
Catalyst for:
• Stereoselective alkylation of aldol reactions1
• Solid phase oligosaccharide synthesis of N-glycans2
• Isomerization and cleavage of allyl ethers of carbohydrates3