amine hydrofluoride

• ChemBase ID: 149363
• Molecular Formular: FN
• Molecular Mass: 33.0051032
• Monoisotopic Mass: 33.00147723
• SMILES: N.F
• Canonical SMILES: N.F
• InChI: InChI=1S/FH.H3N/h1H;1H3
• InChIKey: LDDQLRUQCUTJBB-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: amine hydrofluoride
• IUPAC Traditional name: amine hydrofluoride
• Synonyms: Ammonium fluoride; Ammonium fluoride solution; 氟化铵; 氟化铵 溶液

Database IDs

• CAS Number: 12125-01-8
• EC Number: 235-185-9
• MDL Number: MFCD00011423
• PubChem SID: 24865437; 24852931; 24860581; 162243530; 24846280; 24865139; 24858156; 24865043
• PubChem CID: 16211145

CALCULATED PROPERTIES

• H Acceptors: 1
• H Donor: 1
• LogD (pH = 5.5): -3.7525723
• LogD (pH = 7.4): -2.4393091
• Log P: -0.978
• Molar Refractivity: 15.5149 cm^3
• Polarizability: 2.2600515 Å^3
• Polar Surface Area: 13.59 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Apperance: crystals and lumps
• Boiling Point: 64.6 °C
• Flash Point: 10 °C; 50 °F
• Density: 0.802 g/mL at 25 °C; 1.11 g/mL at 20 °C

Safety Information

• RTECS: BQ6300000
• European Hazard Symbols: Flammable (F); Toxic (T)
• UN Number: 1230; 2505
• German water hazard class: 1
• Hazard Class: 3; 6.1
• Packing Group: 2; 3
• Risk Statements: 11-23/25-36/38; 23/24/25
• Safety Statements: 26-45; 36/37-45; 7-16-24-45
• GHS Pictograms: GHS06
• GHS Signal Word: Danger
• GHS Hazard statements: H301 + H311 + H331; H301-H311-H330; H301-H311-H331
• GHS Precautionary statements: P260-P280-P284-P301 + P310-P310; P261-P280-P301 + P310-P311
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter; Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• RID/ADR: UN 1230 3/PG 2; UN 2505 6.1/PG 3

Product Information

• Purity: ≥97.0%; ≥98%; ≥98.0%; ≥98.0% (F); ≥99.99% trace metals basis
• Concentration: ~40% in H2O; 0.5 M in methanol
• Grade: ACS reagent; puriss. p.a.; purum; SAJ special grade; semiconductor grade PURANAL™ (Honeywell 17767); semiconductor grade VLSI PURANAL™ (Honeywell 17600)
• Ignition Residue: ≤0.005% (as SO4); ≤0.01%
• Impurities: ≤0.005% insolubles; ≤0.1% hexafluorosilicate (as SiF6); ≤1% ammonium hydrogen difluoride (NH4HF2)
• Cation Traces: Ag: ≤5 mg/kg; Al: ≤5 mg/kg; Ba: ≤5 mg/kg; Bi: ≤5 mg/kg; Ca: ≤50 mg/kg; Cd: ≤5 mg/kg; Co: ≤5 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Fe: ≤5 mg/kg; Fe: ≤5 ppm; heavy metals (as Pb): ≤5 ppm; K: ≤20 mg/kg; K: ≤50 mg/kg; Li: ≤5 mg/kg; Mg: ≤5 mg/kg; Mn: ≤5 mg/kg; Mo: ≤5 mg/kg; Na: ≤20 mg/kg; Na: ≤50 mg/kg; Ni: ≤5 mg/kg; Pb: ≤5 mg/kg; Sr: ≤5 mg/kg; Tl: ≤5 mg/kg; Zn: ≤5 mg/kg
• Antion Traces: chloride (Cl-): ≤0.001%; chloride (Cl-): ≤5 mg/kg; hexafluorosilicate (SiF62-): ≤1000 mg/kg; sulfate (SO42-): ≤0.005%; sulfate (SO42-): ≤50 mg/kg
• Linear Formula: NH4F

DETAILS

Sigma Aldrich - 40208

Legal Information
PURANAL is a trademark of Honeywell Specialty Chemicals Seelze GmbH

Sigma Aldrich - 40292

Legal Information
PURANAL is a trademark of Honeywell Specialty Chemicals Seelze GmbH

Sigma Aldrich - 338869

Packaging
25, 100 g in poly bottle
Application
Employed in a new hydrothermal synthesis of complex flourides NaHoF4 and NaEuF4 these interesting compounds have the fluorite structure and are important forsolid-state lasers as well as for photoluminescence and magnetic characteristics.1

Sigma Aldrich - 09737

Other Notes
Reagent for the decomposition of silicates by fusion1,2

Sigma Aldrich - 407259

Packaging
100, 800 mL in Sure/Seal™

Sigma Aldrich - 216011

Packaging
100, 500 g in poly bottle
Application
Employed in a new hydrothermal synthesis of complex flourides NaHoF4 and NaEuF4 these interesting compounds have the fluorite structure and are important for solid-state lasers as well as for photoluminescence and magnetic characteristics.1