bromo(ethenyl)magnesium

• ChemBase ID: 149279
• Molecular Formular: C2H3BrMg
• Molecular Mass: 131.25422
• Monoisotopic Mass: 129.9268538
• SMILES: C=C[Mg]Br
• Canonical SMILES: Br[Mg]C=C
• InChI: InChI=1S/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
• InChIKey: XHHHAXOHMKAOSL-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: bromo(ethenyl)magnesium
• IUPAC Traditional name: bromo(ethenyl)magnesium
• Synonyms: Vinylmagnesium bromide solution; 乙烯基溴化镁 溶液

Database IDs

• CAS Number: 1826-67-1
• MDL Number: MFCD00000042
• Beilstein Number: 3535841
• PubChem SID: 162243447; 24853507; 24855577; 24889972
• PubChem CID: 74584

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.1212
• LogD (pH = 7.4): 1.1212
• Log P: 1.1212
• Molar Refractivity: 18.2175 cm^3
• Polarizability: 8.979965 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 1
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Flash Point: 1.4 °F; -17 °C
• Density: 0.98 g/mL at 20 °C; 0.981 g/mL at 25 °C

Safety Information

• European Hazard Symbols: Corrosive (C); Flammable (F)
• UN Number: 3399
• German water hazard class: 1
• Hazard Class: 4.3
• Packing Group: 2
• Risk Statements: 11-14/15-19-34-37
• Safety Statements: 16-26-36/37/39-43-45
• GHS Pictograms: GHS02; GHS05; GHS07
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H260-H314-H335
• GHS Precautionary statements: P210-P223-P231 + P232-P261-P370 + P378-P422
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 3399 4.3/PG 2
• Supplemental Hazard Statements: May form explosive peroxides., Reacts violently with water.

Product Information

• Concentration: ~1.0 M in THF; 1.0 M in THF
• Grade: purum
• Linear Formula: CH2=CHMgBr

DETAILS

Sigma Aldrich - 257257

Other Notes
Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid
Packaging
1.8 L in Sure-Pac™
200 mL in Sure-Pac™
Recommended products
Angled septum-inlet adapter Z118206 or straight septum-inlet adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter, 13mm I.D. inlet, Z118192 is recommended.

Sigma Aldrich - 225584

Other Notes
Storage below 25°C may cause crystallization. Warm gently to redissolve.
Packaging
100, 800 mL in Sure/Seal™
18 L in Kilo-Lab™
View returnable container options.

Sigma Aldrich - 95008

Caution
Storage below 25°C may cause formation of cryst. magnesium salts; slightly worming and gently swirling should redissolve the solid.