chlorobis(propan-2-yl)silane

• ChemBase ID: 149201
• Molecular Formular: C6H15ClSi
• Molecular Mass: 150.7218
• Monoisotopic Mass: 150.06315469
• SMILES: CC(C)[SiH](C(C)C)Cl
• Canonical SMILES: CC([SiH](C(C)C)Cl)C
• InChI: InChI=1S/C6H15ClSi/c1-5(2)8(7)6(3)4/h5-6,8H,1-4H3
• InChIKey: CGXYLRTYLIHXEE-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: chlorobis(propan-2-yl)silane
• IUPAC Traditional name: chlorodiisopropylsilane
• Synonyms: Diisopropylchlorosilane; Chlorodiisopropylsilane; 二异丙基氯硅烷; 氯二异丙基硅烷

Database IDs

• CAS Number: 2227-29-4
• MDL Number: MFCD00054896
• Beilstein Number: 2231355
• PubChem SID: 162243369; 24863410
• PubChem CID: 6365034

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 1.7761
• LogD (pH = 7.4): 1.7761
• Log P: 1.7761
• Molar Refractivity: 36.7201 cm^3
• Polarizability: 16.518702 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 2
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Boiling Point: 58-60 °C/50 mmHg(lit.)
• Flash Point: 100.4 °F; 38 °C
• Density: 0.883 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.429; n20/D 1.429(lit.)

Safety Information

• European Hazard Symbols: Corrosive (C)
• UN Number: 2986
• German water hazard class: 3
• Hazard Class: 8
• Packing Group: 2
• Risk Statements: 10-34
• Safety Statements: 26-36/37/39-45
• GHS Pictograms: GHS02; GHS05
• GHS Signal Word: Danger
• GHS Hazard statements: H226-H314
• GHS Precautionary statements: P280-P305 + P351 + P338-P310
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 2986 8/PG 2

Product Information

• Purity: ≥98.0% (GC); 99%
• Grade: purum
• Linear Formula: [(CH3)2CH]2SiHCl

DETAILS

Sigma Aldrich - 375896

Packaging
5, 25 g in glass bottle

Sigma Aldrich - 38380

Other Notes
Reagent for the stereoselective reduction of β-hydroxyketones1; Starting material for the preparation of diisopropyl-[5-dimethylamino(1-naphthyl)]silane, a fluorescent OH-selective protecting group reagent (and other diisopropylsilanes)2